Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃

Base Information

• Chemical Name: Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃
• CAS No.: 200207-38-1
• Molecular Formula: CF₃O₃S*C₅₅H₄₇N₂OP₃RhS₄
• Molecular Weight: 1225.15
• Mol file: 200207-38-1.mol

Synonyms:

Chemical Property of Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃

There total 1 articles about Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)⁽¹⁺⁾*CF₃SO₃^(1-)=[Rh(C₇H₄NS₂)2(OP(C₆H₅)2CH₂CCH₃(CH₂P(C₆H₅)2)2)]CF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Rh(CH3CN)3(triphos)}(CF3SO3)3 (128137-75-7) + 2-Mercaptobenzothiazole (149-30-4,118090-09-8) → Rh(C7H4NS2)2(OP(C6H5)2CH2CCH3(CH2P(C6H5)2)2)(1+)*CF3SO3(1-)=[Rh(C7H4NS2)2(OP(C6H5)2CH2CCH3(CH2P(C6H5)2)2)]CF3SO3 (200207-38-1)

Guidance literature:

With air; NaOH; In acetonitrile; Ar-atmosphere; mixing equimolar amts. of ligand and NaOH solns., addn. of 0.5 equiv. of Rh-complex, refluxing for 3 h; concn., pptn. on Et2O addn., recrystn. (MeCN/Et2O or CH2Cl2/hexane underair); elem. anal.;

DOI:10.1016/S0020-1693(97)05549-7

upstream raw materials:

{Rh(CH₃CN)3(triphos)}(CF₃SO₃)3

2-Mercaptobenzothiazole