[(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

Base Information

Chemical Name:[(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]
CAS No.:778640-66-7
Molecular Formula:C₉₄H₉₅P₃Pt₂Si₂
Molecular Weight:1764.04
Hs Code.:

Synonyms:

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Chemical Property of [(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

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Technology Process of [(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

There total 2 articles about [(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: 121441-89-2
2,7-di-tert-butyl-9H-9-silafluorene

: 778640-66-7
[(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

: 891486-30-9
[Pt(triphenylphosphine)2((SiC₂₀H₂₄)2O)]

Guidance literature:: In ⁽²⁾H₈-toluene; (N2 or Ar); using Schlenk techniques; addn. of soln. of H2SiC20H24 in C7D8 to cooled soln. of Pt(PPh3)2(C2H4) in C7D8; monitoring by NMR at 193 K for 3 h; warming to 300 K;
DOI:10.1021/om060009v

Reference yield:

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: [(triphenylphosphine)2Pt(H)(μ-silafluorenyl)(μ-η2-silafluorenyl)Pt(triphenylphosphine)]

: 121441-89-2
2,7-di-tert-butyl-9H-9-silafluorene

: 778640-66-7
[(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

: [(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-silafluorenyl)Pt(triphenylphosphine)]

Guidance literature:: In ⁽²⁾H₈-toluene; (N2 or Ar); using Schlenk techniques; addn. of soln. of H2SiC20H24 in C7D8 to cooled soln. of Pt(PPh3)2C2H4 in C7D8; monitoring by NMR at 223 K;addn. of soln. of (PPh3)3Pt2H(SiC12H8)HSiC12H8 in C7D8 at 195 K; monito ring by NMR at 223 K; warming to r.t.;
DOI:10.1021/om060009v

Reference yield: 28.0%

: 778640-66-7
[(triphenylphosphine)2PtH(μ-3,7-di-tert-butylsilafluorenyl)(μ-η2-3,7-di-tert-butylsilafluorenyl)Pt(triphenylphosphine)]

: 775-12-2
diphenylsilane

: [(triphenylphosphine)Pt(μ-η2-HSiPh2)]2

Guidance literature:: In ⁽²⁾H₈-toluene; (N2); Schlenk line; soln. of Si compd. (1 equiv.) in toluene-d8 was added to soln. of Pt complex in toluene-d8 at 195 K; slowly warmed to 300 K over several h; stored at room temp. for 2 wk;
DOI:10.1021/om061180+