cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

Base Information

Chemical Name:cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]
CAS No.:1188508-67-9
Molecular Formula:C₆₈H₆₆Cl₂O₆P₂Pt
Molecular Weight:1307.2
Hs Code.:

cis-[PtCl<sub>2</sub>((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

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Chemical Property of cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

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Technology Process of cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

There total 3 articles about cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 17457-51-1,17836-09-8,55449-91-7
dichlorobis(dimethylsulfide)platinum(II)

: 1110685-33-0,1188513-84-9,868638-25-9
(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite

: 1188508-67-9
cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; dissolving of (t-Bu)2C6H3OP(OC10H6)2 (2 equiv.) and PtCl2(Me2S)2 (1 equiv.) in CH2Cl2; stirring at room temp. for 2 h; concn. on rotary evaporator; addn. of hexane; pptn., centrifugation; drying under vac., elem. anal.;
DOI:10.1021/om9003237

Reference yield: 59.0%

: 60479-35-8,51014-04-1,41884-65-5
cis-[Pt((CH₃)3CCN)2Cl₂]

: 1110685-33-0,1188513-84-9,868638-25-9
(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite

: 1188508-67-9
cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

Guidance literature:: In tetrahydrofuran; (under N2, Schlenk); Pt-complex added to soln. of ligand in THF, stirredfor 24 h; filtered, solvent removed under reduced pressure, triturated with pentane;
DOI:10.1039/b907333g

Reference yield:

: 60479-35-8,51014-04-1,41884-65-5
cis-[Pt((CH₃)3CCN)2Cl₂]

: 1110685-33-0,1188513-84-9,868638-25-9
(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite

: 1188508-67-9
cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite)2]

: 1188553-34-5
trans-[Pt(μ-Cl)(κ2-(R)-1,1'-binaphthane-2,2'-diyl 2,4-di-tert-butylphenyl phosphite(-1H))]2

Guidance literature:: In toluene; (under N2, Schlenk); Pt-complex added to soln. of ligand in toluene, refluxed for 18 h; solvent removed under reduced pressure, extd. with CH2Cl2, filtered, solvent removed under reduced pressure;
DOI:10.1039/b907333g