Br₂Os₃(CO)10(P(C₆H₅)3)2

Base Information

• Chemical Name: Br₂Os₃(CO)10(P(C₆H₅)3)2
• CAS No.: 101033-34-5
• Molecular Formula: C₄₆H₃₀Br₂O₁₀Os₃P₂
• Molecular Weight: 1535.09
• Mol file: 101033-34-5.mol

Synonyms:

Chemical Property of Br₂Os₃(CO)10(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Br₂Os₃(CO)10(P(C₆H₅)3)2

There total 1 articles about Br₂Os₃(CO)10(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

Br2Os3(CO)12 (21773-71-7) → Os(CO)4PPh3 (21192-24-5,33635-53-9) + Br2Os3(CO)10(P(C6H5)3)2 (101033-34-5) + [Os(P(C6H5)3)2(CO)2Br2] (10170-16-8,17456-72-3,17633-43-1,224577-32-6)

Guidance literature:

With triphenyl phosphine; In tetrahydrofuran; (N2); to a soln. of Os-complex added P(C6H5)3 at room temp.; stirred for 6 h; concn. of mixt. to small vol.; pptn. of yellow solids on addn. of hexane; concd. filtrate cooled to -40 °C to separate Os(CO)4PPH3; primary ppt. extracted with H3CN; solns. evapd. to dryness; Os3(PPh3)2 complex recrystd. at -15°C; solid extractn. residue recrystd.;

upstream raw materials:

Br₂Os₃(CO)12