C₃₂H₃₈OSi

Base Information

• Chemical Name: C₃₂H₃₈OSi
• CAS No.: 1584693-22-0
• Molecular Formula: C₃₂H₃₈OSi
• Molecular Weight: 466.739
• Mol file: 1584693-22-0.mol

Synonyms:

Chemical Property of C₃₂H₃₈OSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₃₈OSi

There total 7 articles about C₃₂H₃₈OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

C29H32OSi + 3-(tert-butyldiphenylsilyl)propene (138566-91-3) → C32H38OSi (1584693-22-0)

Guidance literature:

at -78 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2014.02.018

Reference yield:

3-(tert-butyldiphenylsilyl)propene (138566-91-3) → C32H38OSi (1584693-22-0)

Guidance literature:

Multi-step reaction with 6 steps

1: dirhodium tetraacetate / dichloromethane / 6 h / 20 °C / Inert atmosphere

2: lithium aluminium tetrahydride / diethyl ether / 4.5 h / 0 - 20 °C / Inert atmosphere

3: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 1.5 h / 75 °C / Reflux; Inert atmosphere

4: tetrahydrofuran / 2.5 h / -30 - 0 °C / Inert atmosphere

5: Dess-Martin periodane / dichloromethane / 1.5 h / Inert atmosphere

6: -78 °C / Inert atmosphere

With dirhodium tetraacetate; lithium aluminium tetrahydride; Dess-Martin periodane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate;

DOI:10.1016/j.tetlet.2014.02.018

Reference yield:

trans-2-tert-butyldiphenylsilylmethyl-1-phenylcyclopropyl-1-carboxylic acid ethyl ester → C32H38OSi (1584693-22-0)

Guidance literature:

Multi-step reaction with 5 steps

1: lithium aluminium tetrahydride / diethyl ether / 4.5 h / 0 - 20 °C / Inert atmosphere

2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 1.5 h / 75 °C / Reflux; Inert atmosphere

3: tetrahydrofuran / 2.5 h / -30 - 0 °C / Inert atmosphere

4: Dess-Martin periodane / dichloromethane / 1.5 h / Inert atmosphere

5: -78 °C / Inert atmosphere

With lithium aluminium tetrahydride; Dess-Martin periodane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate;

DOI:10.1016/j.tetlet.2014.02.018

upstream raw materials:

3-(tert-butyldiphenylsilyl)propene

ethyl 2-phenyldiazoacetate