{Fe(CO)3(η4-CH2C(CH3)CHCH2)}

Base Information

Chemical Name:{Fe(CO)3(η4-CH2C(CH3)CHCH2)}
CAS No.:123877-51-0
Molecular Formula:C₈H₈FeO₃
Molecular Weight:207.997
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {Fe(CO)3(η4-CH2C(CH3)CHCH2)}

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Technology Process of {Fe(CO)3(η4-CH2C(CH3)CHCH2)}

There total 1 articles about {Fe(CO)3(η4-CH2C(CH3)CHCH2)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 64135-15-5
diethyl (3-methylbut-2-en-1-yl) phosphate

: 513-35-9
2-methyl-but-2-ene

: 32731-93-4,123877-51-0,127381-01-5
{Fe(CO)3(η4-CH2C(CH3)CHCH2)}

Guidance literature:: With potassium hydroxide; In ethanol; to a soln. of K2Fe(CO)4, prepd. from Fe(CO)5 and KOH in EtOH, was addeddropwise allyl phosphate, mixt. was stirred at room temp. for 1 h; reaction mixt. was distilled to dryness at atm. pressure at give Me2C=CHMe as distillate (GLC anal.), residue was chromd. on SiO2 (light petroleum as eluent) and distilled in vacuo to afford Fe-complex; identified by comparison with authentic sample;
DOI:10.1016/0022-328X(85)80072-3

Reference yield:

: 32731-93-4,123877-51-0,127381-01-5
{Fe(CO)3(η4-CH2C(CH3)CHCH2)}

: 38053-73-5,32511-22-1
(+)-diphenylneomenthylphosphine

: dicarbonyl-eta.4-isoprene((+)-neomenthyldiphenylphosphine)iron

Guidance literature:: With trimethylamine-N-oxide; In not given; prepd. from (η4-isoprene)Fe(CO)3 and (+)-(neomenthyl)PPh2 by Me3NO substitution (A.J. Birch and L.F. Kelly, J. Organomet. Chem., 268 (1985) C5); fractionally crystd. at 0°C from petroleum ether (40-60°C), equimolar mixt. of 2 diastereomers as monitored by (31)P NMR;
DOI:10.1016/S0022-328X(00)99616-5