Chlorbis(diethylamino)phosphonium-chlorid

Base Information

• Chemical Name: Chlorbis(diethylamino)phosphonium-chlorid
• CAS No.: 87163-15-3
• Molecular Formula: C₂₇H₃₅Cl₂N₂P₂*Cl
• Molecular Weight: 555.895
• Mol file: 87163-15-3.mol

Synonyms:

Chemical Property of Chlorbis(diethylamino)phosphonium-chlorid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Chlorbis(diethylamino)phosphonium-chlorid

There total 1 articles about Chlorbis(diethylamino)phosphonium-chlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

bis(diethylamino)chlorophosphine (685-83-6) + triphenylphosphonium dichloromethylide (6779-08-4) → Chlorbis(diethylamino)phosphonium-chlorid (87163-15-3)

Guidance literature:

In toluene; for 4h; Ambient temperature;

Reference yield: 72.0%

Chlorbis(diethylamino)phosphonium-chlorid (87163-15-3) → Chlorbis(diethylamino)<(triphenylphosphoranyliden)methylen>phosphoran (87162-93-4)

Guidance literature:

With Hexamethylphosphorous triamide; 1) Ph-Cl, 6 h, r.t., 2) hexane, reflux;

Reference yield:

Chlorbis(diethylamino)phosphonium-chlorid (87163-15-3) → Bis(diethylamino)(dimethylamino)<(triphenylphosphoranyliden)methylen>phosphoran (87162-99-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 72 percent / tris(dimethylamino)phosphorane / 1) Ph-Cl, 6 h, r.t., 2) hexane, reflux

2: 83 percent / toluene

3: 83 percent / NaH / tetrahydrofuran / 12 h / Ambient temperature

With sodium hydride; Hexamethylphosphorous triamide; In tetrahydrofuran; toluene;

upstream raw materials:

bis(diethylamino)chlorophosphine

triphenylphosphonium dichloromethylide

Downstream raw materials:

Chlorbis(diethylamino)<(triphenylphosphoranyliden)methylen>phosphoran

Bis(diethylamino)(dimethylamino)<(triphenylphosphoranyliden)methylen>phosphoran

Tris(diethylamino)<(triphenylphosphoranyliden)methylen>phosphoran

Bis(diethylamino)(dimethylamino)<(triphenylphosphoranyliden)methyl>phosphonium-chlorid