[Ir₂Cl₂(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))4]

Base Information

• Chemical Name: [Ir₂Cl₂(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))4]
• CAS No.: 898257-44-8
• Molecular Formula: C₁₂₄H₁₃₂Cl₂Ir₂N₈
• Molecular Weight: 2189.81
• Mol file: 898257-44-8.mol

Synonyms:

Chemical Property of [Ir₂Cl₂(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir₂Cl₂(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))4]

There total 1 articles about [Ir₂Cl₂(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine (898257-45-9) + iridium(III) trichloride hydrate → [Ir2Cl2(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine(1-))4] (898257-44-8)

Guidance literature:

In 2-ethoxy-ethanol; water; (N2); IrCl3*H2O and the organic ligand in a mixture of 2-ethoxyethanol and water refluxed for 25 h; majority of 2-ethoxyethanol removed out under vacuum; filtered; washed with ethanol and acetone; recrystallized from a mixture of CH2Cl2, toluene, and hexane (1:1:1);

DOI:10.1246/cl.2006.538

Reference yield: 60.0%

[Ir2Cl2(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine(1-))4] (898257-44-8) + acetylacetone enol (26567-75-9) → [(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine(1-))2Ir(acac)] (882513-36-2)

Guidance literature:

With sodium carbonate; In 2-ethoxy-ethanol; (N2); Ir-complex, acetyl acetone, and Na2CO3 in 2-ethoxyethanol refluxedfor 15 h; majority of 2-ethoxyethanol removed out under vacuum; excess water added; precipitate filtered, dried; chromy.(aluminum oxide/CH2Cl2 column);

DOI:10.1246/cl.2006.538

upstream raw materials:

N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine

Downstream raw materials:

[(N,N-di(4-tert-butylphenyl)-4-(2-pyridyl)benzenamine^(1-))2Ir(acac)]