C₁₇H₁₂O₆

Base Information

• Chemical Name: C₁₇H₁₂O₆
• CAS No.: 1417716-47-2
• Molecular Formula: C₁₇H₁₂O₆
• Molecular Weight: 312.279
• Mol file: 1417716-47-2.mol

Synonyms:

Chemical Property of C₁₇H₁₂O₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₇H₁₂O₆

There total 4 articles about C₁₇H₁₂O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C12H7BrO5 (1417716-31-4) + C12H7BrO5 (1417716-45-0) + 1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene (73311-51-0) → C17H12O6 (1417716-33-6) + C17H12O6 (1417716-47-2)

Guidance literature:

C₁₂H₇BrO₅; C₁₂H₇BrO₅; 1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene; In benzene; at 20 ℃; Inert atmosphere;

With silica gel; In benzene; Overall yield = 84 %; Inert atmosphere;

DOI:10.1021/jo302364h

Reference yield:

methyl 3,5-dihydroxy-2-naphthoate (185989-39-3) → C17H12O6 (1417716-47-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: salcomine; oxygen / N,N-dimethyl-formamide / 3 h

2.1: bromine / acetic acid / Inert atmosphere

2.2: 0.08 h / Reflux; Inert atmosphere

2.3: 1 h / 20 °C / Inert atmosphere

With salcomine; bromine; oxygen; In acetic acid; N,N-dimethyl-formamide; 2.3: |Diels-Alder Cycloaddition;

DOI:10.1021/jo302364h

Reference yield:

methyl 3-hydroxy-5,8-dioxo-5,8-dihydronaphthalene-2-carboxylate (1417716-29-0) + 1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene (73311-51-0) → C17H12O6 (1417716-33-6) + C17H12O6 (1417716-47-2) + C18H14O6 + C18H14O6

Guidance literature:

methyl 3-hydroxy-5,8-dioxo-5,8-dihydronaphthalene-2-carboxylate; With bromine; In acetic acid; Inert atmosphere;

With sodium acetate; In acetic acid; for 0.0833333h; Reflux; Inert atmosphere;

1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene; In toluene; at 20 ℃; for 1h; Overall yield = 65 %; regioselective reaction; Inert atmosphere;

DOI:10.1021/jo302364h

upstream raw materials:

methyl 3,5-dihydroxy-2-naphthoate

methyl 3-hydroxy-5,8-dioxo-5,8-dihydronaphthalene-2-carboxylate

1-methoxy-3-methyl-1-trimethylsilyloxy-1,3-butadiene

C₁₂H₇BrO₅