(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

Base Information

Chemical Name:(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate
CAS No.:131618-32-1
Molecular Formula:C₂₆H₃₆O₆S
Molecular Weight:476.634
Hs Code.:

Synonyms:

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Chemical Property of (5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

Chemical Property:

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Technology Process of (5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

There total 3 articles about (5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 183312-54-1
3-benzyloxypropylmagnesium bromide

: 131618-32-1
(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

Guidance literature:: Multi-step reaction with 2 steps

1: 62 percent / CuI / tetrahydrofuran / 1.5 h / -15 °C

2: 1.) SOCl₂, Et₃N, 2.) NaIO₄, RuCl₃*xH₂O / 1.) CH₂Cl₂, ice bath, 30 min 2.) CCl₄-MeCN, 0 deg C, 2h

With ruthenium trichloride; sodium periodate; copper(l) iodide; thionyl chloride; triethylamine; In tetrahydrofuran;
DOI:10.1021/jo00004a011

Reference yield:

: 2,5-bis(methylsulfonyloxy)-1,6-hexanediol

: 131618-32-1
(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

Guidance literature:: Multi-step reaction with 3 steps

1: 20percent KOH / methanol / 1 h / ice bath

2: 62 percent / CuI / tetrahydrofuran / 1.5 h / -15 °C

3: 1.) SOCl₂, Et₃N, 2.) NaIO₄, RuCl₃*xH₂O / 1.) CH₂Cl₂, ice bath, 30 min 2.) CCl₄-MeCN, 0 deg C, 2h

With ruthenium trichloride; potassium hydroxide; sodium periodate; copper(l) iodide; thionyl chloride; triethylamine; In tetrahydrofuran; methanol;
DOI:10.1021/jo00004a011

Reference yield:

: 131618-31-0
(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol

: 131618-32-1
(5S,8S)-1,12-Bis(benzyloxy)-5,8-dodecanediol Cyclic Sulfate

Guidance literature:: With ruthenium trichloride; sodium periodate; thionyl chloride; triethylamine; Yield given. Multistep reaction; 1.) CH₂Cl₂, ice bath, 30 min 2.) CCl₄-MeCN, 0 deg C, 2h;
DOI:10.1021/jo00004a011