(PPh₃)(1,10-phenanthroline)CuN₃

Base Information

Chemical Name:(PPh₃)(1,10-phenanthroline)CuN₃
CAS No.:94365-51-2
Molecular Formula:C₃₀H₂₃CuN₅P
Molecular Weight:548.066
Hs Code.:

(PPh<sub>3</sub>)(1,10-phenanthroline)CuN<sub>3</sub>

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Chemical Property of (PPh₃)(1,10-phenanthroline)CuN₃

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Technology Process of (PPh₃)(1,10-phenanthroline)CuN₃

There total 2 articles about (PPh₃)(1,10-phenanthroline)CuN₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 66-71-7
1,10-Phenanthroline

: [Cu(N₃)(P(C₆H₅)3)2]2

: 94365-51-2
(PPh₃)(1,10-phenanthroline)CuN₃

Guidance literature:: In diethyl ether; under N2; Schlenk techniques; soln./suspn. of 1,10-phenanthroline added to soln. of (Cu(N3)(PPh3)2)2 at 273 K; stirred overnight at room temp.; ligand-to-metal molar ratio of 1:1; filtered off; ppt. washed with diethyl ether-ethanol (3:1); recrystd. from acetonitrile-diethyl ether (1:1); elem.anal.;
DOI:10.1016/S0277-5387(01)00895-6

Reference yield:

: 66-71-7
1,10-Phenanthroline

: azidobis(triphenylphosphine)copper(I)

: 94365-51-2
(PPh₃)(1,10-phenanthroline)CuN₃

Guidance literature:: In dichloromethane; addn. of N2C12H8 to soln. of ((PPh3)2CuN3)2 (ligand:Cu ratio = 1.1) with stirring;; evapg. to dryness after 1 h; treating residue several times with toluene; filtering, washing with n-hexane and drying; elem. anal.;;
DOI:10.1016/0022-328X(84)80531-8

Reference yield: 80.0%

: 75-15-0,12122-00-8
carbon disulfide

: 94365-51-2
(PPh₃)(1,10-phenanthroline)CuN₃

: 603-35-0
triphenylphosphine

: 94365-53-4
(PPh₃)(1,10-phenanthroline)Cu(NC(S)SN₂)

Guidance literature:: In benzene; PPh3 and CS2 added to benzene soln. of Cu(N3)(PPh3)(1,10-phenanthroline); stirred for 2 h; conctd.; ppt. filtered; washed with n-hexane; elem.anal.;
DOI:10.1016/S0277-5387(01)00895-6