Technology Process of methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4[2-(methoxycarbonyl)propyl]-1H-pyrrolo(2,3-d)carbazole-6-carboxylate
There total 6 articles about methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4[2-(methoxycarbonyl)propyl]-1H-pyrrolo(2,3-d)carbazole-6-carboxylate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylamine;
In
tetrahydrofuran; methanol;
for 10h;
Heating;
DOI:10.1039/b209990j
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 77 percent / diisopropylamine; n-butyl lithium / hexamethylphosphoric acid triamide; tetrahydrofuran; hexane / -78 - -40 °C
2: H2SO4 / 0.75 h
3: pyridinium chlorochromate; NaOAc / CH2Cl2 / 0.5 h
4: methanol / 20 h / 20 °C
5: tetrahydrofuran / 48 h / Heating
6: Et3N / methanol; tetrahydrofuran / 10 h / Heating
With
n-butyllithium; sulfuric acid; sodium acetate; triethylamine; diisopropylamine; pyridinium chlorochromate;
In
tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane;
DOI:10.1039/b209990j
- Guidance literature:
-
Multi-step reaction with 5 steps
1: H2SO4 / 0.75 h
2: pyridinium chlorochromate; NaOAc / CH2Cl2 / 0.5 h
3: methanol / 20 h / 20 °C
4: tetrahydrofuran / 48 h / Heating
5: Et3N / methanol; tetrahydrofuran / 10 h / Heating
With
sulfuric acid; sodium acetate; triethylamine; pyridinium chlorochromate;
In
tetrahydrofuran; methanol; dichloromethane;
DOI:10.1039/b209990j
