(S(p))-1-(diphenylphosphanyl)-2-ethylferrocene

Base Information

Chemical Name:(S(p))-1-(diphenylphosphanyl)-2-ethylferrocene
CAS No.:55650-55-0
Molecular Formula:C₂₄H₂₃FeP
Molecular Weight:398.267
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S(p))-1-(diphenylphosphanyl)-2-ethylferrocene

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Technology Process of (S(p))-1-(diphenylphosphanyl)-2-ethylferrocene

There total 2 articles about (S(p))-1-(diphenylphosphanyl)-2-ethylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 913095-08-6,819800-53-8
(Sp)-2-(diphenylphosphino)-1-vinylferrocene

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 55650-55-0,1013943-67-3
(S(p))-1-(diphenylphosphanyl)-2-ethylferrocene

Guidance literature:: With sodium acetate; In tetrahydrofuran; water; under Ar atm. to soln. Fe complex and p-toluenesulfonyl hydrazine in THFaq. soln. AcONa was added and heated at reflux for 20 h; aq. soln. K2CO3 was added and stirred for 1 h, Et2O was added, prg. layer was dried over MgSO4 and evapd., residue was purified by column chromy. on silica (hexane-Et2O 5:1), solvent was removed in vacuo;
DOI:10.1016/j.jorganchem.2007.11.016

Reference yield: 78.0%

: 74286-13-8
(R)-1-diphenylphosphinyl-2-ethylferrocene

: 1013943-67-3,55650-55-0
(R)-1-diphenylphosphino-2-ethylferrocene

Guidance literature:: With lithium aluminium tetrahydride; In dibutyl ether; benzene; addition of soln. of LiAlH4 in Bu2O over 10 min, heated at 80-85°C for 4.5 h, N2 atm.; chromy. (alumina, benzene); elem. anal.;
DOI:10.1246/bcsj.53.1138