Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃

Base Information

• Chemical Name: Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃
• CAS No.: 1020269-37-7
• Molecular Formula: C₇H₈*C₄₈H₄₂P₂PtSi
• Molecular Weight: 996.115
• Mol file: 1020269-37-7.mol

Synonyms:

Chemical Property of Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃

There total 5 articles about Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + 1,1,2,2-tetramethyldisilane (814-98-2) + toluene (108-88-3,15644-74-3,16713-13-6) → Pt(P(C6H5)3)2H(SiH(C6H5)2)*C6H5CH3 (1020269-37-7)

Guidance literature:

In chloroform; (inert atm., Schlenk) to a toluene-soln. of complex was added a toluene-soln. of disilane at -30°C, the mixt. was stirred at -10°Cto -5°C for 1 h; pentane was added, allowed to stand in the chilled box at -30°C; elem. anal.;

DOI:10.1021/om800012s

Reference yield:

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) → Pt(P(C6H5)3)2H(SiH(C6H5)2)*C6H5CH3 (1020269-37-7)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform

2: ⁽²⁾H₈-toluene

In chloroform; ⁽²⁾H₈-toluene;

DOI:10.1021/om800012s

Reference yield:

Pt(P(C6H5)3)2(SiH(C6H5)2)2 (1020269-32-2) → Pt(P(C6H5)3)2H(SiH(C6H5)2)*C6H5CH3 (1020269-37-7)

Guidance literature:

In ⁽²⁾H₈-toluene; (inert atm., Schlenk) C7D8, -20°C; not sepd., detected by NMR spectra;

DOI:10.1021/om800012s

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

1,1,2,2-tetramethyldisilane

toluene

Pt(P(C₆H₅)3)2(SiH(C₆H₅)2)2