RhClP(O(CH₂)3P(C₆H₅)2)3RhCl(C₈H₁₂)

Base Information

• Chemical Name: RhClP(O(CH₂)3P(C₆H₅)2)3RhCl(C₈H₁₂)
• CAS No.: 471865-39-1
• Molecular Formula: C₅₃H₆₀Cl₂O₃P₄Rh₂
• Molecular Weight: 1145.67
• Mol file: 471865-39-1.mol

Synonyms:

Chemical Property of RhClP(O(CH₂)3P(C₆H₅)2)3RhCl(C₈H₁₂)

Chemical Property:

Purity/Quality:

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Technology Process of RhClP(O(CH₂)3P(C₆H₅)2)3RhCl(C₈H₁₂)

There total 1 articles about RhClP(O(CH₂)3P(C₆H₅)2)3RhCl(C₈H₁₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + P(O(CH2)3P(C6H5)2)3 (471865-30-2) → RhClP(O(CH2)3P(C6H5)2)3RhCl(C8H12) (471865-39-1)

Guidance literature:

In benzene; under N2; soln. of ligand in benzene added dropwise to soln. of Rh-complex in benzene, stirred for 2 h at ambient temp.; solvent was removed in vacuo, pptd. with benzene and hexane; elem. anal.;

DOI:10.1021/om020098l

Reference yield: 97.0%

P(O(CH2)3P(C6H5)2)3 (471865-30-2) + RhClP(O(CH2)3P(C6H5)2)3RhCl(C8H12) (471865-39-1) → [RhClP(O(CH2)3P(C6H5)2)3RhClP(O(CH2)3P(C6H5)2)3]

Guidance literature:

In benzene; under N2; soln. of ligand in benzene added dropwise to soln. of Rh-complex in benzene, stirred for 2 h at ambient temp.; solvent was removed in vacuo, pptd. with benzene and hexanes; elem. anal.;

DOI:10.1021/om020098l

Reference yield: 96.0%

C6H5P(O(CH2)3P(C6H5)2)2 (471865-29-9) + RhClP(O(CH2)3P(C6H5)2)3RhCl(C8H12) (471865-39-1) → RhClP(O(CH2)3P(C6H5)2)3RhClPC6H5(O(CH2)3P(C6H5)2)2 (471865-41-5)

Guidance literature:

In benzene; under N2; soln. of ligand in benzene added dropwise to soln. of Rh-complex in benzene, stirred for 3 h at ambient temp.; solvent was removed in vacuo, pptd. with benzene and hexanes; elem. anal.;

DOI:10.1021/om020098l

upstream raw materials:

P(O(CH₂)3P(C₆H₅)2)3

Downstream raw materials:

RhClP(O(CH₂)3P(C₆H₅)2)3RhClPC₆H₅(O(CH₂)3P(C₆H₅)2)2