6-Fluorochrysene

Base Information

Chemical Name:6-Fluorochrysene
CAS No.:388-06-7
Molecular Formula:C₁₈H₁₁F
Molecular Weight:246.284
Hs Code.:

Synonyms:

Suppliers and Price of 6-Fluorochrysene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-Fluorochrysene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Fluorochrysene

There total 6 articles about 6-Fluorochrysene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1,1-difluoro-3-[1-(naphthalen-1-yl)cyclopent-3-en-1-yl]propa-1,2-diene

: 388-06-7
6-Fluorochrysene

: 34236-47-0
6-fluorobenzophenanthrene

Guidance literature:: 1,1-difluoro-3-[1-(naphthalen-1-yl)cyclopent-3-en-1-yl]propa-1,2-diene; With indium(III) bromide; In dichloromethane; at 20 ℃; for 0.5h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 2h; Reflux;
DOI:10.1002/asia.202000069

Reference yield:

: 1-(naphthalen-1-yl)cyclopent-3-ene-1-carbonitrile

: 388-06-7
6-Fluorochrysene

: 34236-47-0
6-fluorobenzophenanthrene

Guidance literature:: Multi-step reaction with 5 steps

1.1: diisobutylaluminium hydride / toluene / 1.5 h / -78 °C / Inert atmosphere

2.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -95 °C / Inert atmosphere

2.2: -95 - -30 °C / Inert atmosphere

2.3: 1.5 h / -30 - 0 °C / Inert atmosphere

3.1: zinc / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

4.1: indium(III) bromide / 1,2-dichloro-ethane / 0.5 h / 20 °C / Inert atmosphere; Glovebox

5.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / 1,2-dichloro-ethane / 1.5 h / Inert atmosphere; Reflux; Glovebox

With indium(III) bromide; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; lithium diisopropyl amide; In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/anie.201302740

Reference yield:

: C₁₆H₁₄O

: 388-06-7
6-Fluorochrysene

: 34236-47-0
6-fluorobenzophenanthrene

Guidance literature:: Multi-step reaction with 4 steps

1.1: lithium diisopropyl amide / tetrahydrofuran / 0.5 h / -95 °C / Inert atmosphere

1.2: -95 - -30 °C / Inert atmosphere

1.3: 1.5 h / -30 - 0 °C / Inert atmosphere

2.1: zinc / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

3.1: indium(III) bromide / 1,2-dichloro-ethane / 0.5 h / 20 °C / Inert atmosphere; Glovebox

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / 1,2-dichloro-ethane / 1.5 h / Inert atmosphere; Reflux; Glovebox

With indium(III) bromide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; lithium diisopropyl amide; In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1002/anie.201302740