bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

Base Information

Chemical Name:bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)
CAS No.:51869-65-9
Molecular Formula:C₂₄H₂₄S₂Ti
Molecular Weight:424.467
Hs Code.:

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Chemical Property of bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

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Technology Process of bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

There total 1 articles about bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: LiCH₂SC₆H₅*2C₄H₈O

: 51869-65-9
bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

Guidance literature:: In diethyl ether; toluene; byproducts: LiCl; under Ar, Cp2TiCl2 suspended in ether/toluene, treated at -20°C with cooled to -20°C soln. of PhSCH2Li*2THF in toluene, stirred at -20°C for 1 h; ether distd. off in vac., filtered, concd. at -5°C, pentane added dropwise, product filtered off, washed with cold pentane, dried in vac., recrystd. from butadiene or from toluene/pentane at -20°C; elem. anal.;
DOI:10.1016/0022-328X(85)80036-X

Reference yield: 31.0%

: 51869-65-9
bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

: bis(benzenethiolato)bis(η5-cyclopentadienyl)titanium

: [(C₅H₅)2TiSC₆H₅]2

Guidance literature:: In toluene; under Ar, Cp2Ti(CH2SPh)2 heated on water bath for 4 h; ppt. filtered off, recrystd. from C6H6, mother liquor concd., ppt. filtered off, recrystd. from C6H6; elem. anal.;
DOI:10.1016/0022-328X(85)80036-X

Reference yield: 30.0%

: 51869-65-9
bis(η5-cyclopentadienyl)bis(thioanisolyl)titanium(IV)

: [(C₅H₅)2TiSC₆H₅]2

Guidance literature:: In benzene; byproducts: PhSCH3; under Ar, Cp2Ti(CH2SPh)2 dissolved in C6H6, heated at reflux for 4 h; filtered, washed with C6H6, dried in vac.;
DOI:10.1016/0022-328X(85)80036-X