Technology Process of nickel(II) octaethylporphyrin N-oxide
There total 1 articles about nickel(II) octaethylporphyrin N-oxide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
ammonia;
In
methanol; dichloromethane;
addn. of MeOH satd. with NH3 and nickel acetate to a soln. of octaethylporphyrin N-oxide in CH2Cl2, refluxing under Ar for 24 h; cooling, evapn. in vac., dissolving in CH2Cl2, washing (aq. NH3, H2O), concg. in vac., column chromy. (silica gel, hexane/CH2Cl2) gives a pink fraction of Ni-octaethylporphyrin, elution with CH2Cl2, evapn. in vac., recrystn. (CH2Cl2/MeOH), elem. anal.;
DOI:10.1021/ja00294a033
- Guidance literature:
-
In
xylene;
refluxing Ni(II) octaethylporphyrin N-oxide in xylene under Ar for 30 min; evapn., chromy. (silica gel, hexane/benzene (1:1)): first band containsNi(II) octaethylporphyrin, second band contains Ni(II) octaethyloxochlorin, third band not identified (5:2:3 ratio);
DOI:10.1016/S0020-1693(00)84399-6
