(R)-3-methylhexyl tosylate

Base Information

• Chemical Name: (R)-3-methylhexyl tosylate
• CAS No.: 86423-93-0
• Molecular Formula: C₁₄H₂₂O₃S
• Molecular Weight: 270.393
• Mol file: 86423-93-0.mol

Synonyms:

Chemical Property of (R)-3-methylhexyl tosylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-3-methylhexyl tosylate

There total 4 articles about (R)-3-methylhexyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-1-citronellyl acetate (20425-54-1,67650-82-2) → (R)-3-methylhexyl tosylate (86423-93-0)

Guidance literature:

Multi-step reaction with 4 steps

1: 1.) O₃, NaHCO₃ 2.) Me₂S / 1.) MeOH, -56 deg C, 3 h, 2.) room temp., overnight

2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / 1 h / Heating

3: 50percent aq. KOH / bis-(2-hydroxy-ethyl) ether / 1.5 h / Heating

4: pyridine / 3 h

With pyridine; potassium hydroxide; dimethylsulfide; sodium hydrogencarbonate; ozone; hydrazine hydrate; In diethylene glycol;

Reference yield:

(R)-(+)-6-acetoxy-4-methylhexanal (79517-78-5,84145-52-8) → (R)-3-methylhexyl tosylate (86423-93-0)

Guidance literature:

Multi-step reaction with 3 steps

1: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / 1 h / Heating

2: 50percent aq. KOH / bis-(2-hydroxy-ethyl) ether / 1.5 h / Heating

3: pyridine / 3 h

With pyridine; potassium hydroxide; hydrazine hydrate; In diethylene glycol;

Reference yield:

Acetic acid (R)-6-hydrazono-3-methyl-hexyl ester → (R)-3-methylhexyl tosylate (86423-93-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 50percent aq. KOH / bis-(2-hydroxy-ethyl) ether / 1.5 h / Heating

2: pyridine / 3 h

With pyridine; potassium hydroxide; In diethylene glycol;

upstream raw materials:

(3R)-3-Methylhexan-1-ol

p-toluenesulfonyl chloride

(R)-(+)-6-acetoxy-4-methylhexanal

(R)-1-citronellyl acetate