6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Base Information

Chemical Name:6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine
CAS No.:341037-01-2
Molecular Formula:C₃₈H₅₀O₇S₈Si
Molecular Weight:903.424
Hs Code.:

6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Synonyms:

Suppliers and Price of 6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

There total 9 articles about 6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 307543-49-3
5-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiin-2-one

: 337965-54-5
6,6-Bis(methoxyethoxymethoxymethyl)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepin-2-one

: 341037-01-2
6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

: 341036-93-9
2-[6',6'-Bis(methoxyethoxymethoxymethyl)-6',7'-dihydro-5'H-[1,3]dithiolo[4,5-b][1,4]dithiepin-2'-ylidene]-6,6-bis(methoxyethoxymethoxymethyl)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Guidance literature:: With triethyl phosphite; at 110 ℃; for 5h;
DOI:10.1039/b007660k

Reference yield:

: 3296-90-0
bis(bromomethyl)bis(hydroxymethyl)methane

: 341037-01-2
6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Guidance literature:: Multi-step reaction with 4 steps

1: 25 percent / ethanol / Heating

2: 95 percent / iPr₂NEt / CH₂Cl₂ / 20 °C

3: 97 percent / Hg(OAc)2; AcOH / CHCl₃ / 3 h / 20 °C

4: 37 percent / P(OEt)3 / 5 h / 110 °C

With mercury(II) diacetate; acetic acid; N-ethyl-N,N-diisopropylamine; triethyl phosphite; In ethanol; dichloromethane; chloroform;
DOI:10.1039/b007660k

Reference yield:

: 136787-49-0
3-(tert-butyldiphenylsilyloxy)prop-1-ene

: 341037-01-2
6,6-Bis(methoxyethoxymethoxymethyl)-2-(5',6'-dihydro-5'-tert-butyldiphenylsilyloxymethyl[1,3]dithiolo[4,5-b][1,4]dithiin-2'-ylidene)-6,7-dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / Br₂ / CHCl₃ / 3 h / 20 °C

2: 54 percent / tetrahydrofuran / 12 h / 0 - 20 °C

3: 99 percent / glacial acetic acid; mercuric acetete / CHCl₃ / 2 h / 20 °C

4: 37 percent / P(OEt)3 / 5 h / 110 °C

With mercury(II) diacetate; bromine; acetic acid; triethyl phosphite; In tetrahydrofuran; chloroform;
DOI:10.1039/b007660k