endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

Base Information

Chemical Name:endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane
CAS No.:132267-83-5
Molecular Formula:C₁₄H₁₈
Molecular Weight:190.265
Hs Code.:

endo-2-phenyl<5,5,6,6-<sup>2</sup>H4>bicyclo<2.2.2>octane

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

Chemical Property:

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Technology Process of endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

There total 6 articles about endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 130913-08-5,132340-54-6,132340-55-7
endo-5-phenylbicyclo<2.2.2>octan-2-one

: 132267-83-5,132340-56-8
endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

Guidance literature:: With diclazuril; deuteroacetic acid; mercury; zinc; for 2h; Heating;
DOI:10.1021/jo00003a028

Reference yield:

: 57346-05-1
Bicyclo<2.2.2>octane-2,4-dione

: 132267-83-5,132340-56-8
endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 6 steps

1: 53 percent / p-TsOH / benzene / 1 h / Heating

2: cyclohexane; diethyl ether / 2 h / -78 °C

3: 5percent aq. H₂SO₄ / CH₂Cl₂ / Ambient temperature

4: 1) HCl(g) / 1) CH₂Cl₂, 0 deg C, 35 min, 2) 60 deg C, 30-100 mm Hg, 2 h

5: 44 percent / H₂ / 5percent Pd-C / ethanol / 0 °C / 760 Torr

6: 86 percent / AcOD, DCl, Zn-Hg / 2 h / Heating

With hydrogenchloride; diclazuril; deuteroacetic acid; sulfuric acid; hydrogen; toluene-4-sulfonic acid; mercury; zinc; palladium on activated charcoal; In diethyl ether; ethanol; dichloromethane; cyclohexane; benzene;
DOI:10.1021/jo00003a028

Reference yield:

: 132435-30-4
5-(ethylenedioxy)bicyclo<2.2.2>octan-2-one

: 132267-83-5,132340-56-8
endo-2-phenyl<5,5,6,6-²H4>bicyclo<2.2.2>octane

Guidance literature:: Multi-step reaction with 5 steps

1: cyclohexane; diethyl ether / 2 h / -78 °C

2: 5percent aq. H₂SO₄ / CH₂Cl₂ / Ambient temperature

3: 1) HCl(g) / 1) CH₂Cl₂, 0 deg C, 35 min, 2) 60 deg C, 30-100 mm Hg, 2 h

4: 44 percent / H₂ / 5percent Pd-C / ethanol / 0 °C / 760 Torr

5: 86 percent / AcOD, DCl, Zn-Hg / 2 h / Heating

With hydrogenchloride; diclazuril; deuteroacetic acid; sulfuric acid; hydrogen; mercury; zinc; palladium on activated charcoal; In diethyl ether; ethanol; dichloromethane; cyclohexane;
DOI:10.1021/jo00003a028