C₃₇H₅₀O₅Si

Base Information

Chemical Name:C₃₇H₅₀O₅Si
CAS No.:221056-83-3
Molecular Formula:C₃₇H₅₀O₅Si
Molecular Weight:602.886
Hs Code.:

C<sub>37</sub>H<sub>50</sub>O<sub>5</sub>Si

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₃₇H₅₀O₅Si

Chemical Property:

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Technology Process of C₃₇H₅₀O₅Si

There total 13 articles about C₃₇H₅₀O₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₈H₅₁F₃O₈SSi

: 221056-83-3
C₃₇H₅₀O₅Si

: C₃₇H₅₀O₅Si

Guidance literature:: With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; potassium carbonate; In toluene; at 100 ℃; for 7h; Yield given; Yields of byproduct given;
DOI:10.1016/S0040-4039(98)02298-9

Reference yield:

: C₃₈H₅₁F₃O₈SSi

: C₃₅H₄₆O₃Si

: C₃₇H₅₂O₅Si

: 221056-83-3
C₃₇H₅₀O₅Si

: C₃₇H₅₀O₅Si

Guidance literature:: With palladium diacetate; (R)-2,2'-bis[bis(3-methylphenyl)phosphino]-1,1'-binaphthyl; potassium carbonate; In toluene; at 100 ℃; for 1.5h; Yields of byproduct given;
DOI:10.1016/S0040-4039(98)02298-9

Reference yield:

: 26357-25-5,40996-90-5,127728-66-9
trans-7aβ-Methyl-1,5-dioxo-3aα,4β,5,6,7,7a-hexahydroindan-4α-carbonsaeuremethylester

: 221056-83-3
C₃₇H₅₀O₅Si

Guidance literature:: Multi-step reaction with 11 steps

1: 1.) NaH, 2.) Pd(OAc)2, PPh₃ / 1.) THF, 0 deg C-> r.t., 45 min, 2.) THF, 60 deg C, 30 min

2: 80 percent / TMSOTf / CH₂Cl₂ / 72 h / -78 - -40 °C

3: 99 percent / H₂O, LiCl / dimethylformamide / 8 h / 150 °C

4: KHMDS / tetrahydrofuran / 0.5 h / -78 °C

5: 1.) mCPBA, KHCO₃, 2.) NH₄F / 1.) CH₂Cl₂, - 40 deg C -> -5 deg C, 2.) MeOH, H₂O, 0 deg C, 30 min

6: 1.) Cu(OAc)2*H₂O, 2.) DBU / 1.) MeOH, 0 deg C -> r.t., 2.) CH₂Cl₂, 0 deg C, 10 min

7: 95 percent / i-Pr₂NEt / CH₂Cl₂ / 0.33 h / -78 °C

8: 62 percent / NaBH₄, CeCl₃*7H₂O / methanol / 0.67 h / 0 °C

9: 83 percent / P₂O₅ / CHCl₃ / 0.33 h / Ambient temperature

10: 1.) 9-BBN, H₂O, 2.) PdCl₂(dppf) K₃PO₄ / 1.) THF, 0 deg C -> r.t., 90 min, 2.) THF, reflux, 3 h

11: Pd(OAc)2, (R)-Tol-BINAP, K₂CO₃ / toluene / 1.5 h / 100 °C

With palladium diacetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; ammonium fluoride; sodium tetrahydroborate; potassium phosphate; 9-borabicyclo[3.3.1]nonane dimer; cerium(III) chloride; copper diacetate; (R)-2,2'-bis[bis(3-methylphenyl)phosphino]-1,1'-binaphthyl; trimethylsilyl trifluoromethanesulfonate; water; phosphorus pentoxide; potassium hexamethylsilazane; sodium hydride; potassium carbonate; potassium hydrogencarbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium chloride; In tetrahydrofuran; methanol; dichloromethane; chloroform; N,N-dimethyl-formamide; toluene;
DOI:10.1016/S0040-4039(98)02298-9