[PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

Base Information

Chemical Name:[PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]
CAS No.:312720-65-3
Molecular Formula:C₃₂H₄₀Cl₄P₂PdSn₂
Molecular Weight:972.269
Hs Code.:

[PdCl<sub>2</sub>(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>CH<sub>2</sub>Sn(Cl)(CH<sub>3</sub>)2)2]

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Suppliers and Price of [PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

Chemical Property:

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Technology Process of [PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

There total 1 articles about [PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.2%

: 84678-23-9
{2-(chlorodimethylstannyl)ethyl}diphenylphosphine

: 55528-77-3,14873-91-7,27199-13-9
trans-PdCl₂(S(C₂H₅)2)2

: 312720-65-3,312624-42-3
[PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

Guidance literature:: In dichloromethane; byproducts: Et2S; all operations under dry Ar; soln. of Sn compd. added dropwise to soln.of Pd complex, mixt. allowed to stand at room temp. for several h; solvent and by-prod. evapd. in vac., residue crystd. by dissolving in CH2Cl2, hexane added till turbidity, filtered, dried; cis/trans not isolated, detected by NMR; elem. anal.;
DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F

Reference yield: 64.7%

: 312720-65-3,312624-42-3
[PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

: 134110-44-4,312720-59-5
[Pd(P(C₆H₅)2CH₂CH₂Sn(CH₃)2)2]

Guidance literature:: With Na amalgam; In tetrahydrofuran; byproducts: NaCl; all operations under dry Ar; soln. of Pd-Sn complex added dropwise to stirred soln. of 1% Na amalgam, mixt. allowed to stand at room temp. for 5 h; filtered, solvent evapd., oily residue not crystd., purifn. by ppt. from CH2Cl2/hexane; elem. anal.;
DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F

Reference yield: 43.1%

: 312720-65-3,312624-42-3
[PdCl₂(P(C₆H₅)2CH₂CH₂Sn(Cl)(CH₃)2)2]

: trans-[Pd(Cl)(PPh₂CH₂CH₂SnMe₂)(PPh₂CH₂CH₂Sn(Cl)Me₂)]

Guidance literature:: With graphite potassium; In tetrahydrofuran; byproducts: KCl; all operations under dry Ar; soln. of Pd-Sn complex added dropwise to stirred suspn. of C8K (cooled to -78°C), mixt. stirred at room temp. for a night; filtered, filtrate concd., with hexane overlayered; elem. anal.;
DOI:10.1002/1521-3749(200010)626:10<2185::AID-ZAAC2185>3.0.CO;2-F