2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Base Information

Chemical Name:2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide
CAS No.:135696-98-9
Molecular Formula:C₂₈H₁₈O₃S₂
Molecular Weight:466.581
Hs Code.:

Synonyms:

Suppliers and Price of 2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

There total 3 articles about 2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 102555-71-5,124414-36-4,124414-37-5
1,1'-binaphthalene-2,2'-dithiol

: 135696-98-9,135759-79-4
2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / boron trifluoride etherate / CH₂Cl₂ / 1.) 0 deg C, 4 h, 2.) r.t., 3 h

2: 92 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / -10 °C

3: 98 percent / potassium permanganate, magnesium sulfate / acetone / 2 h / -20 °C

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2 h, 2.) -78 deg C, 2 h, then warmed to -40 deg C over 3 h

With potassium permanganate; n-butyllithium; boron trifluoride diethyl etherate; magnesium sulfate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetone;
DOI:10.1021/jo00014a027

Reference yield:

: 124414-31-9,141900-56-3,462094-18-4
2H-dinaphtho<2,1-d:1',2'-f><1,3>dithiepine

: 135696-98-9,135759-79-4
2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / -10 °C

2: 98 percent / potassium permanganate, magnesium sulfate / acetone / 2 h / -20 °C

3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2 h, 2.) -78 deg C, 2 h, then warmed to -40 deg C over 3 h

With potassium permanganate; n-butyllithium; magnesium sulfate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetone;
DOI:10.1021/jo00014a027

Reference yield:

: 123434-93-5,135759-69-2
Dinaphtho<2,1-d:1',2'-f><1,3>dithiepine S-oxide

: 135696-98-9,135759-79-4
2-Benzoylbinaphtho<2,1-d:1',2'-f><1,3>dithiepine S,S-dioxide

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / potassium permanganate, magnesium sulfate / acetone / 2 h / -20 °C

2: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2 h, 2.) -78 deg C, 2 h, then warmed to -40 deg C over 3 h

With potassium permanganate; n-butyllithium; magnesium sulfate; In acetone;
DOI:10.1021/jo00014a027