2-Ethylideneadamantane

Base Information

Chemical Name:2-Ethylideneadamantane
CAS No.:13376-16-4
Molecular Formula:C₁₂H₁₈
Molecular Weight:162.275
Hs Code.:
DSSTox Substance ID:DTXSID50383592
Nikkaji Number:J305.647C
Mol file:13376-16-4.mol

Synonyms:2-ethylideneadamantane;13376-16-4;ethylidenadamantane;DTXSID50383592;DDSATBSDGAPDPM-OIXVIMQBSA-N;DDSATBSDGAPDPM-UHFFFAOYSA-N

Suppliers and Price of 2-Ethylideneadamantane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
2-Ethylideneadamantane 95+%
1g
$ 772.00

American Custom Chemicals Corporation
2-ETHYLIDENEADAMANTANE 95.00%
5MG
$ 496.97

Total 5 raw suppliers

Chemical Property of 2-Ethylideneadamantane

Chemical Property:

Melting Point:5.0 °C
Boiling Point:220 °C
Density:1.035±0.06 g/cm3(Predicted)
Storage Temp.:2-8°C
XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:162.140850574
Heavy Atom Count:12
Complexity:194

Purity/Quality:

99% ^*data from raw suppliers

2-Ethylideneadamantane 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=C1C2CC3CC(C2)CC1C3

Technology Process of 2-Ethylideneadamantane

There total 14 articles about 2-Ethylideneadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: (1r,3r,5R*,7S*)-2-(iodomethylene)adamantane

: 917-54-4
methyllithium

: 13376-16-4
(1r,3r,5R*,7S*)-2-ethylideneadamantane

Guidance literature:: With iron(II) acetylacetonate; DavePhos; In toluene; at 23 ℃; for 0.5h; stereospecific reaction; Glovebox; Inert atmosphere;
DOI:10.1021/acs.orglett.9b00394

Reference yield: 43.0%

: 700-58-3
2-Adamantanone

: 925-90-6
ethylmagnesium bromide

: 13376-16-4
(1r,3r,5R*,7S*)-2-ethylideneadamantane

Guidance literature:: 2-Adamantanone; ethylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

With phosphonic acid diethyl ester; In tetrahydrofuran; at 20 ℃; Inert atmosphere;
DOI:10.1039/c001931c

Reference yield: 32.0%

: 700-58-3
2-Adamantanone

: 1530-32-1
ethyltriphenylphosphonium bromide

: 13376-16-4
(1r,3r,5R*,7S*)-2-ethylideneadamantane

Guidance literature:: ethyltriphenylphosphonium bromide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 22 ℃; for 0.333333h; Schlenk technique; Inert atmosphere;

2-Adamantanone; In tetrahydrofuran; hexane; at -78 - 22 ℃; for 21.5h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.organomet.1c00086