1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)-

Base Information

• Chemical Name: 1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)-
• CAS No.: 123415-45-2
• Molecular Formula: C32H54O4
• Molecular Weight: 502.778
• DSSTox Substance ID: DTXSID00478487
• Nikkaji Number: J1.014.415I
• Wikidata: Q82311900
• Mol file: 123415-45-2.mol

Synonyms:123415-45-2;1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)-;2,5-Bis(dodecyloxy)terephthalaldehyde;2,5-didodecoxyterephthalaldehyde;2,5-didodecoxyterephthalaldehyd;YSZC335;SCHEMBL18901651;DTXSID00478487;BS-45953;CS-0170327;F75468

Chemical Property of 1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)-

Chemical Property:

• XLogP3: 12
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 26
• Exact Mass: 502.40221020
• Heavy Atom Count: 36
• Complexity: 451

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCOC1=CC(=C(C=C1C=O)OCCCCCCCCCCCC)C=O

Technology Process of 1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)-

There total 9 articles about 1,4-Benzenedicarboxaldehyde, 2,5-bis(dodecyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2,5-bis(hydroxymethyl)-1,4-bis(dodecyloxy)benzene (237757-97-0) → 1,4-di(n-dodecyloxy)benzene-2,5-dicarboxaldehyde (123415-45-2)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane;

DOI:10.1246/cl.1999.1129

Reference yield: 88.0%

N,N-dimethyl-formamide (68-12-2,33513-42-7) + 1,4-bis(dodecyloxy)-2,5-diiodobenzene (145483-66-5) → 1,4-di(n-dodecyloxy)benzene-2,5-dicarboxaldehyde (123415-45-2)

Guidance literature:

1,4-bis(dodecyloxy)-2,5-diiodobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

DOI:10.1021/ma049243s

Reference yield: 79.0%

1,4-bis(bromomethyl)-2,5-bis-(dodecyloxy)benzene (122996-59-2) → 1,4-di(n-dodecyloxy)benzene-2,5-dicarboxaldehyde (123415-45-2)

Guidance literature:

With sodium hydrogencarbonate; dimethyl sulfoxide; at 115 ℃; for 0.5h;

DOI:10.1081/SCC-200046485

upstream raw materials:

2,5-bis(hydroxymethyl)-1,4-bis(dodecyloxy)benzene

1,4-bis(bromomethyl)-2,5-bis-(dodecyloxy)benzene

N,N-dimethyl-formamide

1,4-bis(dodecyloxy)-2,5-diiodobenzene

Downstream raw materials:

1,4-bis(cyanomethyl)-2,5-bis(dodecyloxy)benzene

E,E-1,4-bis(4-tert-butylstyryl)-2,5-di(n-dodecyloxy)benzene

1,4-Bis-dodecyloxy-2,5-bis-[(E)-2-(4-nitro-phenyl)-vinyl]-benzene

1,4-bis((E)-4-bromostyryl)-2,5-bis(dodecyloxy)benzene