9,9-Dihexylfluorene

Base Information

• Chemical Name: 9,9-Dihexylfluorene
• CAS No.: 123863-97-8
• Molecular Formula: C25H34
• Molecular Weight: 334.545
• DSSTox Substance ID: DTXSID50408592
• Nikkaji Number: J1.187.508D
• Wikidata: Q82214114
• Mol file: 123863-97-8.mol

Synonyms:9,9-dihexylfluorene;123863-97-8;9,9-dihexyl-9H-Fluorene;9H-Fluorene, 9,9-dihexyl-;9,9-Dihexyl fluorene;9,9-di-n-hexylfluorene;YSCK0444;DTXSID50408592;LQQKFGSPUYTIRB-UHFFFAOYSA-N;YEA86397;MFCD14584648;AKOS030528407;SB66512;AS-58479;CS-0168274;D4327;FT-0732174;T70165

Chemical Property of 9,9-Dihexylfluorene

Chemical Property:

• Melting Point: 32°C(lit.)
• PSA: 0.00000
• LogP: 7.89390
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Dichloromethane (Slightly)
• XLogP3: 9.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 334.266051085
• Heavy Atom Count: 25
• Complexity: 334

Purity/Quality:

99% ^*data from raw suppliers

9,9-Dihexylfluorene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC1(C2=CC=CC=C2C3=CC=CC=C31)CCCCCC

Technology Process of 9,9-Dihexylfluorene

There total 3 articles about 9,9-Dihexylfluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9H-fluorene (86-73-7) + 1-bromo-hexane (111-25-1) → 9,9-dihexyl-9H-fluorene (123863-97-8)

Guidance literature:

9H-fluorene; With n-butyllithium; In tetrahydrofuran; at -78 ℃;

1-bromo-hexane; In tetrahydrofuran; at -78 - 20 ℃; for 12h; Further stages.;

DOI:10.1002/chem.200501037

Reference yield: 85.0%

9H-fluorene (86-73-7) + 1-Chlorohexane (544-10-5) → 9,9-dihexyl-9H-fluorene (123863-97-8)

Guidance literature:

9H-fluorene; With tetra-(n-butyl)ammonium iodide; sodium hydroxide; In water; for 0.75h; Inert atmosphere;

1-Chlorohexane; In water; at 70 ℃; for 7h; Inert atmosphere;

DOI:10.1021/jo100028d

Reference yield:

9H-fluorene (86-73-7) → 9,9-dihexyl-9H-fluorene (123863-97-8)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/j.tetlet.2008.05.107

upstream raw materials:

9H-fluorene

1-bromo-hexane

1-Chlorohexane

Downstream raw materials:

2,7-bis(bromomethyl)-9,9'-dihexyl-9H-fluorene

9,9-dihexyl-2-(2'-phenyl-1-ethynyl)fluorene

9,9-dihexyl-2,7-bis(2-phenylethynyl)fluorene

C₆₁H₅₈