(-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

Base Information

• Chemical Name: (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene
• CAS No.: 120624-78-4
• Molecular Formula: C₃₀H₂₂BrF₃O₃
• Molecular Weight: 567.402

Synonyms:

Chemical Property of (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

There total 4 articles about (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

(R)-methoxytrifluoromethylphenylacetyl chloride (20445-33-4,39637-99-5) + (+/-)-trans-10-Bromo-9-hydroxy-9,10,11,12-tetrahydrobenzopyrene (88767-14-0) → (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene (120624-78-4,120708-39-6) + (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene (120624-78-4)

Guidance literature:

With pyridine; dmap; for 20h; Ambient temperature;

DOI:10.1039/P19880003013

Reference yield: 41.0%

(R)-methoxytrifluoromethylphenylacetyl chloride (20445-33-4,39637-99-5) + (+/-)-trans-10-Bromo-9-hydroxy-9,10,11,12-tetrahydrobenzopyrene (88767-14-0) → (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene (120624-78-4,120708-39-6) + (-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene (120624-78-4)

Guidance literature:

With pyridine; dmap; for 20h; Ambient temperature;

DOI:10.1039/P19880003013

Reference yield:

9,10-Dihydrobenzopyrene (66788-01-0) → (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene (120624-78-4,120708-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / N-bromosuccinimide / tetrahydrofuran; H₂O / 0 °C

2: 37 percent / 4-dimethylaminopyridine, pyridine, / 20 h / Ambient temperature

With pyridine; dmap; N-Bromosuccinimide; In tetrahydrofuran; water;

DOI:10.1039/P19880003013

upstream raw materials:

(R)-methoxytrifluoromethylphenylacetyl chloride

(+/-)-trans-10-Bromo-9-hydroxy-9,10,11,12-tetrahydrobenzopyrene

9,10-Dihydrobenzopyrene

Downstream raw materials:

(-)-(9S,10R)-9,10-Epoxy-9,10,11,12-tetrahydrobenzopyrene

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