mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

Base Information

Chemical Name:mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I
CAS No.:95402-12-3
Molecular Formula:C₅₀H₄₅FeIN₃P₂*I
Molecular Weight:1059.53
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

Chemical Property:

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Technology Process of mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

There total 1 articles about mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 53687-41-5,54002-76-5
I₂Fe(CH₃C₆H₄NC)4

: 95402-12-3
mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

Guidance literature:: With C₂H₄(P(C₆H₅)2)2; In toluene; under Ar, toluene soln. of educts refluxed for 1 h; ppt. filtered, washed with diethyl ether, recrystd. from CH2Cl2/EtOH, elem. anal.;
DOI:10.1016/0022-328X(84)80603-8

Reference yield:

: 95402-12-3
mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

: 121241-53-0
(1,2-bis(diphenylphosphino)ethane)tris(4-methyl-phenyl isocyanide) iron⁽⁰⁾

Guidance literature:: In tetrahydrofuran; dry oxygen-free argon atmosphere; addn. of excess of sodium amalgam to a stirred suspension of mer-{FeI(dppe)(CNPh)3}I in THF, stirred for 1 h, red soln. was filtered, solvent was removed in vacuo, residue extracted with toluene, filtration; no isolation;

Reference yield:

: 95402-12-3
mer-{FeI(1,2-bis(diphenylphosphino)ethane)(4-methyl-phenyl isocyanide)3}I

: silver perchlorate

: mer-{Fe(OClO₃)(dppe)(p-tolyl isocyanide)3}ClO₄

Guidance literature:: In dichloromethane; byproducts: AgI; under Ar, mixt. of mer-(FeI(dppe)(4-CH3C6H4NC)3)I and AgClO4 (molar ratio 1:2) stirred for 1h; filtered, concd., petroleum ether added to ppt. the product, elem. anal.;
DOI:10.1016/0022-328X(84)80603-8