Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂

Base Information

• Chemical Name: Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂
• CAS No.: 235751-75-4
• Molecular Formula: C₃₀H₂₂FeO₅P₂
• Molecular Weight: 580.296
• Mol file: 235751-75-4.mol

Synonyms:

Chemical Property of Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂

There total 1 articles about Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

Fe(CO)4(P(C6H5)2COCH3) (235751-69-6) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → Fe(CO)4(P(C6H5)2C(OP(C6H5)2))CH2 (235751-75-4)

Guidance literature:

With LiN(i)Pr₂; In tetrahydrofuran; byproducts: LiCl; Ar-atmosphere; addn. of slight excess of LiN(i)Pr2 to Fe-complex soln. at -78°C, stirring (-78 to -50°C, 45 min), addn. of slight excess of PPh2Cl at -78°C, stirring (-78°C to 20°C,overnight); filtration, evapn., extn. into pentane, standing at -15°C, evapn.;

DOI:10.1016/S0022-328X(98)01223-6

upstream raw materials:

Fe(CO)4(P(C₆H₅)2COCH₃)

chloro-diphenylphosphine