(OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))]

Base Information

• Chemical Name: (OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))]
• CAS No.: 440634-55-9
• Molecular Formula: C₅₂H₄₅NO₅P₂Ru
• Molecular Weight: 926.951
• Mol file: 440634-55-9.mol

Synonyms:

Chemical Property of (OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))]

There total 1 articles about (OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)} (114818-52-9,104713-03-3,261948-85-0,325146-81-4,104621-48-9) + 1,1,1-trideuteromethanol (1849-29-2) + Methyl 2-acetamidoacrylate (35356-70-8) → (OC-6-43-C)-[RuH(CH3COO)((S)-binap)((2,3-η-κO1')-(methyl α-(acetamido)acrylate))] (440634-55-9)

Guidance literature:

In methanol; N,N-dimethyl-formamide; Ru complex dissolved in DMF soln. of CH3OH-CD3OH mixture, exposed to 2 atm of H2 for 20 h, enamide soln. in CD3OH added under H2; not isolated, NMR;

DOI:10.1021/ja010982n

upstream raw materials:

Ru(OCOCH₃)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}

1,1,1-trideuteromethanol

Methyl 2-acetamidoacrylate

Refernces