[Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

Base Information

Chemical Name:[Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]
CAS No.:458569-29-4
Molecular Formula:C₃₅H₅₆IN₂O₂Y
Molecular Weight:752.652
Hs Code.:

[Y((C<sub>6</sub>H<sub>3</sub>-2,6-(isopropyl)2)N(CH<sub>2</sub>)3N(C<sub>6</sub>H<sub>3</sub>-2,6-(isopropyl)2))I(THF)2]

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Suppliers and Price of [Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

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Technology Process of [Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

There total 2 articles about [Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 13470-38-7
yttrium(III) iodide

: K₂((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))

: 458569-29-4
YI(C₄H₈O)2(C₃H₇)2C₆H₃N(CH₂)3NC₆H₃(C₃H₇)2

Guidance literature:: In tetrahydrofuran; byproducts: KI; stoichiometric amount, THF, overnight at room temp.; slow cooling of a toluene soln. to -45°C;

Reference yield: 18.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 13470-38-7
yttrium(III) iodide

: K₂((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))

: 458569-29-4
[Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

Guidance literature:: In tetrahydrofuran; byproducts: C6H3(CH(CH3)2)2NH(CH2)3NHC6H3(CH(CH3)2)2, KI; (N2 or Ar); using Schlenk techniques; slurrying of K2(C6H3(CH(CH3)2)2N(CH2)3NC6H3(CH(CH3)2)2) (1 equiv.) and YI3 (1 equiv.) in THF (0°C);stirring overnight at room temp.; removal of solvent under reduced pressure, drying in vac. for 1 h; addn.of toluene; filtration of suspn.; concn.; crystn. at -45°C for 3 days; elem. anal.;
DOI:10.1039/b400149d

Reference yield: 43.0%

: 458569-29-4
[Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))I(THF)2]

: 40949-94-8
potassium hexamethylsilazane

: 708268-38-6
[Y((C₆H₃-2,6-(isopropyl)2)N(CH₂)3N(C₆H₃-2,6-(isopropyl)2))(THF)(N(SiMe₃)2)]

Guidance literature:: In toluene; (N2 or Ar); using Schlenk techniques; dissolving of Y(C6H3(CH(CH3)2)2N(CH2)3NC6H3(CH(CH3)2)2)I(THF)2 and KN(SiMe3)2 in toluene (0°C); stirring overnight at 20°C; removal of solvent, drying in vac. for 1 h; addn. of pentane; filtration, concn., crystn. at -45°C; elem. anal.;
DOI:10.1039/b400149d