Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

Base Information

Chemical Name:Ni((P(C₆H₅)2)2C₂H₄)(CS₃)
CAS No.:81097-98-5
Molecular Formula:C₂₇H₂₄NiP₂S₃
Molecular Weight:565.323
Hs Code.:

Ni((P(C<sub>6</sub>H<sub>5</sub>)2)2C<sub>2</sub>H<sub>4</sub>)(CS<sub>3</sub>)

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Chemical Property of Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

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Technology Process of Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

There total 2 articles about Ni((P(C₆H₅)2)2C₂H₄)(CS₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: hexaaquanickel(II) tetrafluoroborate

: 13472-44-1,19086-11-4,66905-14-4,66905-15-5,66905-63-3
trithiocarbonic acid ; sodium salt

: 81097-98-5
Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

Guidance literature:: With dppe; In ethanol; dichloromethane; soln. of Na2CS3*H2O in EtOH was added to mixt. of Ni-complex in EtOH and ligand in CH2Cl2 under N2; concd., washed with EtOH and light petroleum, recrystd. from CH2Cl2-EtOH; elem. anal.;
DOI:10.1039/DT9820000799

Reference yield:

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 584-10-1
potassium trithiocarbonate

: 81097-98-5
Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

Guidance literature:: In water; acetone; stirred for 1 h, N2 atm.; filtration, pptn. with water, filtration, washing a ppt. with diethyl ether, recrystn. (dichloromethane/diethyl ether); elem. anal.;
DOI:10.1021/ic00136a056

Reference yield: 70.0%

: 15038-41-2
pentacarbonyl(tetrahydrofuran)chromium⁽⁰⁾

: 81097-98-5
Ni((P(C₆H₅)2)2C₂H₄)(CS₃)

: NiCS₃(C₆H₅)4P₂(CH₂)2Cr(CO)5

Guidance literature:: In tetrahydrofuran; Cr-complex in THF was added to Ni-complex in THF for 3 h under N2; solvent was evapd. at reduced pressure, residue extd. with CH2Cl2, EtOHwas added, solvent was evapd., recrystd. from EtOH; elem. anal.;
DOI:10.1039/DT9820000799