4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl

Base Information

• Chemical Name: 4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl
• CAS No.: 125337-31-7
• Molecular Formula: C30H38O6
• Molecular Weight: 494.61900
• Hs Code.: 2918990090
• DSSTox Substance ID: DTXSID00697797
• Nikkaji Number: J676.427D
• Wikidata: Q82627811
• Mol file: 125337-31-7.mol

Synonyms:125337-31-7;4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl;([1,1'-Biphenyl]-4,4'-diylbis(oxy))bis(hexane-6,1-diyl) diacrylate;6-[4-[4-(6-prop-2-enoyloxyhexoxy)phenyl]phenoxy]hexyl prop-2-enoate;2-Propenoic acid, 1,1'-[[1,1'-biphenyl]-4,4'-diylbis(oxy-6,1-hexanediyl)] ester;ACRYLIC ACID 6-[4/'-(6-ACRYLOYLOXY-HEXYLOXY)BIPHENYL-4-YLOXY]HEXYL ESTER;SCHEMBL723159;DTXSID00697797;4,4/'-Bis[6-(acryloyloxy)hexyloxy]biphenyl;4,4'-bis-(6-(acryloyloxy)-hexyloxy)biphenyl;[([1,1'-Biphenyl]-4,4'-diyl)bis(oxy)hexane-6,1-diyl] diprop-2-enoate;6-[(4'-{[6-(PROP-2-ENOYLOXY)HEXYL]OXY}-[1,1'-BIPHENYL]-4-YL)OXY]HEXYL PROP-2-ENOATE

Chemical Property of 4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl

Chemical Property:

• PSA: 71.06000
• LogP: 6.69040
• XLogP3: 7.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 21
• Exact Mass: 494.26683893
• Heavy Atom Count: 36
• Complexity: 563

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCCCCCOC1=CC=C(C=C1)C2=CC=C(C=C2)OCCCCCCOC(=O)C=C
• Uses: BAB 6 can be used to prepare polymer-stabilized liquid crystal material for high-throughput inkjet printing.

Technology Process of 4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl

There total 4 articles about 4,4'-Bis[6-(acryloyloxy)hexyloxy]biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

acryloyl chloride (814-68-6,25189-84-8) + N,N-bis(2-hydroxyethyl)-9-anthracenemethanamine (97087-90-6) → 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl (125337-31-7)

Guidance literature:

With N,N-dimethyl-aniline; In 1,4-dioxane; at 0 - 50 ℃; for 26h; Inert atmosphere;

DOI:10.1039/d1tc04354d

Reference yield:

4,4'-Dihydroxybiphenyl (92-88-6) → 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl (125337-31-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / tetrahydrofuran

2: triethylamine

With triethylamine; sodium hydroxide; In tetrahydrofuran;

Reference yield:

1-bromo-6-hexanol (4286-55-9) → 4,4'-bis(6-(acryloyloxy)-hexyloxy)biphenyl (125337-31-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / tetrahydrofuran

2: triethylamine

With triethylamine; sodium hydroxide; In tetrahydrofuran;

upstream raw materials:

6-chloro-1-hexanol

4,4'-Dihydroxybiphenyl

acryloyl chloride

N,N-bis(2-hydroxyethyl)-9-anthracenemethanamine