ditosyliminomolybdenum dichloride

Base Information

• Chemical Name: ditosyliminomolybdenum dichloride
• CAS No.: 256660-46-5
• Molecular Formula: C₁₄H₁₄Cl₂MoN₂O₄S₂
• Molecular Weight: 505.254
• Mol file: 256660-46-5.mol

Synonyms:

Chemical Property of ditosyliminomolybdenum dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ditosyliminomolybdenum dichloride

There total 2 articles about ditosyliminomolybdenum dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

molybdenum(VI) oxychloride + toluenesulfonylsulfinylamide (4104-47-6) → ditosyliminomolybdenum dichloride (256660-46-5)

Guidance literature:

In toluene; byproducts: SO2; Ar atm.; refluxing (3 h); filtn., washing (toluene), drying (vac.); elem. anal.;

DOI:10.1002/(sici)1521-3749(199912)625:12<2125::aid-zaac2125>3.0.co;2-y

Reference yield:

toluenesulfonylsulfinylamide (4104-47-6) + dioxomolybdenum(VI) dichloride (13637-68-8) → ditosyliminomolybdenum dichloride (256660-46-5)

Guidance literature:

In not given; byproducts: SO2;

DOI:10.1002/zaac.200390137

Reference yield: 52.0%

ditosyliminomolybdenum dichloride (256660-46-5) + trimethylphosphane (594-09-2) → [MoCl2(NSO2C6H4CH3)((CH3)3P)3]

Guidance literature:

In tetrahydrofuran; byproducts: TosN=PMe3; Ar atm.; excess of PMe3, heating (60°C, 2 h), cooling (room temp.), addn. of Et2O; filtn., evapn. (vac.), dissoln. (CH3CN), crystn. (4°C); elem. anal.;

DOI:10.1002/(sici)1521-3749(199912)625:12<2125::aid-zaac2125>3.0.co;2-y

upstream raw materials:

toluenesulfonylsulfinylamide

dioxomolybdenum(VI) dichloride