C₃₆H₄₈O₈Si

Base Information

• Chemical Name: C₃₆H₄₈O₈Si
• CAS No.: 1192365-20-0
• Molecular Formula: C₃₆H₄₈O₈Si
• Molecular Weight: 636.858
• Mol file: 1192365-20-0.mol

Synonyms:

Chemical Property of C₃₆H₄₈O₈Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₄₈O₈Si

There total 10 articles about C₃₆H₄₈O₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

C36H48O7Si → C36H46O8Si (1192365-19-7) + C36H48O8Si (1192365-20-0)

Guidance literature:

With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; Inert atmosphere;

DOI:10.1002/asia.200800429

Reference yield:

C58H78O7Si3 (1018988-60-7) → C36H46O8Si (1192365-19-7) + C36H48O8Si (1192365-20-0)

Guidance literature:

Multi-step reaction with 7 steps

1.1: 2,6-di-tert-butyl-4-methylpyridine; 2,3-dicyano-5,6-dichloro-p-benzoquinone / acetonitrile / 20 °C / Inert atmosphere

2.1: sodium tetrahydroborate / tetrahydrofuran; ethanol / -40 - -30 °C / Inert atmosphere

3.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 13 °C / Inert atmosphere

4.1: lithium borohydride / tetrahydrofuran / Inert atmosphere; Reflux

4.2: 4 h / 20 °C / Inert atmosphere

5.1: lithium borohydride / tetrahydrofuran / 26.5 h / 20 °C / Inert atmosphere; Reflux

5.2: 4 h / 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / Inert atmosphere

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / Inert atmosphere

With sodium tetrahydroborate; lithium borohydride; 2,6-di-tert-butyl-4-methylpyridine; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; Dess-Martin periodane; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; ethanol; dichloromethane; acetonitrile; 2.1: Luche reduction;

DOI:10.1002/asia.200800429

Reference yield:

C52H66O7Si2 (1018988-59-4) → C36H46O8Si (1192365-19-7) + C36H48O8Si (1192365-20-0)

Guidance literature:

Multi-step reaction with 10 steps

1.1: sodium tetrahydroborate / ethanol / 2 h / -78 °C / Inert atmosphere

2.1: dichloromethane / 1 h / 20 °C / Inert atmosphere; Molecular sieve

2.2: 39 h / 20 °C / Inert atmosphere

3.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

4.1: 2,6-di-tert-butyl-4-methylpyridine; 2,3-dicyano-5,6-dichloro-p-benzoquinone / acetonitrile / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate / tetrahydrofuran; ethanol / -40 - -30 °C / Inert atmosphere

6.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 13 °C / Inert atmosphere

7.1: lithium borohydride / tetrahydrofuran / Inert atmosphere; Reflux

7.2: 4 h / 20 °C / Inert atmosphere

8.1: lithium borohydride / tetrahydrofuran / 26.5 h / 20 °C / Inert atmosphere; Reflux

8.2: 4 h / 20 °C / Inert atmosphere

9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / Inert atmosphere

10.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / Inert atmosphere

With sodium tetrahydroborate; lithium borohydride; 2,6-di-tert-butyl-4-methylpyridine; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; ethanol; dichloromethane; acetonitrile; 5.1: Luche reduction;

DOI:10.1002/asia.200800429

upstream raw materials:

C₅₂H₆₆O₇Si₂

C₅₂H₆₈O₇Si₂

C₅₂H₆₄O₇Si₂

C₅₈H₇₈O₇Si₃

Refernces