(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl

Base Information

• Chemical Name: (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl
• CAS No.: 1356002-89-5
• Molecular Formula: C₂₂H₂₄ClN₂NiP
• Molecular Weight: 441.563
• Mol file: 1356002-89-5.mol

Synonyms:

Chemical Property of (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl

There total 2 articles about (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N-(dimethylaminoethyl)-2-diphenylphosphinoaniline (858135-33-8) + (1,2-dimethoxyethane)dichloronickel(II) (29046-78-4) → (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl (1356002-89-5)

Guidance literature:

With (C₂H₅)3N; In tetrahydrofuran; (N2); a soln. of ligand added to a suspn. of Ni complex at room temp., (C2H5)3N added, stirred at room temp. for 1 h; evapd. (vac.), triturated with pentane, extd. (C6H6), passed through a pad of Celite, evapd. (vac.);

DOI:10.1039/c1dt11338k

Reference yield: 80.0%

(1,2-dimethoxyethane)dichloronickel(II) (29046-78-4) + (Li(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H)))2 (1356002-87-3) → (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl (1356002-89-5)

Guidance literature:

In tetrahydrofuran; (N2); a soln. of Li complex added dropwise at -35°C to a suspn. of Ni complex, stirred at room temp. for 2 d; evapd. (vac.), extd. (C6H6), filtered, evapd. (vac.);

DOI:10.1039/c1dt11338k

Reference yield: 99.0%

(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiCl (1356002-89-5) + ethylmagnesium chloride (2386-64-3) → (N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiEt (1356002-92-0)

Guidance literature:

With O(C₂H₄)2O; In tetrahydrofuran; (N2); Mg compd. added dropwise to a soln. contg. Ni complex and O(C2H4)2O at -35°C, stirred at room temp. for 2 h; evapd. (vac.), extd. (C6H6), filtered, evapd. (vac.); elem. anal.;

DOI:10.1039/c1dt11338k

upstream raw materials:

N-(dimethylaminoethyl)-2-diphenylphosphinoaniline

(1,2-dimethoxyethane)dichloronickel(II)

(Li(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H)))2

Downstream raw materials:

(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiBr

(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiI

(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))Ni(i-Bu)

(N-(dimethylaminoethyl)-2-diphenylphosphinoaniline(-1H))NiEt