2((C₆H₅)3P)2N⁽¹⁺⁾*WNi₆(CO)17^(2-)=(((C₆H₅)3P)2N)2(WNi₆(CO)17)

Base Information

• Chemical Name: 2((C₆H₅)3P)2N⁽¹⁺⁾*WNi₆(CO)17^(2-)=(((C₆H₅)3P)2N)2(WNi₆(CO)17)
• CAS No.: 79466-70-9
• Molecular Formula: C₁₇Ni₆O₁₇W*2C₃₆H₃₀NP₂
• Molecular Weight: 2089.34
• Mol file: 79466-70-9.mol

Synonyms:

Chemical Property of 2((C₆H₅)3P)2N⁽¹⁺⁾*WNi₆(CO)17^(2-)=(((C₆H₅)3P)2N)2(WNi₆(CO)17)

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of 2((C₆H₅)3P)2N⁽¹⁺⁾*WNi₆(CO)17^(2-)=(((C₆H₅)3P)2N)2(WNi₆(CO)17)

There total 1 articles about 2((C₆H₅)3P)2N⁽¹⁺⁾*WNi₆(CO)17^(2-)=(((C₆H₅)3P)2N)2(WNi₆(CO)17) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

tungsten hexacarbonyl (14040-11-0) + bis(bis(triphenylphosphine)iminium) dodecacarbonylhexanickelate → 2((C6H5)3P)2N(1+)*WNi6(CO)17(2-)=(((C6H5)3P)2N)2(WNi6(CO)17) (79466-70-9)

Guidance literature:

In tetrahydrofuran; dichloromethane; Irradiation (UV/VIS); under inert atmosphere, soln. of W(CO)6 in THF photolyzed at 25°C for 20 min, cooled to 0°C, Ni-complex (molar ratio 2:1) in CH2Cl2 added, stirred for 1 h, cooled; solvent removed under vac., dissolved in CH2Cl2, filtered on Celite, ether added to filtrate, stood overnight at -10°C, washed with ether, dried under vac.; elem. anal.;

DOI:10.1021/ic50226a085

upstream raw materials:

tungsten hexacarbonyl