(S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

Base Information

Chemical Name:(S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate
CAS No.:1357622-44-6
Molecular Formula:C₁₂H₁₄BrNO₄
Molecular Weight:316.151
Hs Code.:

Synonyms:

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Chemical Property of (S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

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Technology Process of (S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

There total 10 articles about (S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1357622-26-4
(R,E)-2-(3-bromophenoxy)methyl-5-methylhex-3-enyl acetate

: 1357622-44-6
(S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

Guidance literature:: Multi-step reaction with 9 steps

1.1: potassium hydroxide / methanol / 0 °C

2.1: triethylamine / dichloromethane / -30 °C / Inert atmosphere

3.1: sodium azide / N,N-dimethyl-formamide / 50 °C / Inert atmosphere

4.1: triphenylphosphine / tetrahydrofuran; water / 0 - 50 °C / Inert atmosphere

5.1: dicyclohexyl-carbodiimide / dichloromethane / 0 - 20 °C / Inert atmosphere

6.1: ozone / methanol; dichloromethane / -78 °C / Inert atmosphere

6.2: -78 °C / Inert atmosphere

7.1: sodium tetrahydroborate / methanol; dichloromethane / -78 - -3 °C / Inert atmosphere

8.1: Jones reagent / acetone / 2 h / 0 °C / Inert atmosphere

8.2: pH 2 / Inert atmosphere

9.1: tetrahydrofuran / 0 °C / Inert atmosphere

With sodium tetrahydroborate; Jones reagent; sodium azide; ozone; triethylamine; dicyclohexyl-carbodiimide; triphenylphosphine; potassium hydroxide; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1039/c1ob06632c

Reference yield:

: 1357622-40-2
(S,E)-2-((3-bromophenoxy)methyl)-5-methylhex-3-en-1-ol

: 1357622-44-6
(S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

Guidance literature:: Multi-step reaction with 8 steps

1.1: triethylamine / dichloromethane / -30 °C / Inert atmosphere

2.1: sodium azide / N,N-dimethyl-formamide / 50 °C / Inert atmosphere

3.1: triphenylphosphine / tetrahydrofuran; water / 0 - 50 °C / Inert atmosphere

4.1: dicyclohexyl-carbodiimide / dichloromethane / 0 - 20 °C / Inert atmosphere

5.1: ozone / methanol; dichloromethane / -78 °C / Inert atmosphere

5.2: -78 °C / Inert atmosphere

6.1: sodium tetrahydroborate / methanol; dichloromethane / -78 - -3 °C / Inert atmosphere

7.1: Jones reagent / acetone / 2 h / 0 °C / Inert atmosphere

7.2: pH 2 / Inert atmosphere

8.1: tetrahydrofuran / 0 °C / Inert atmosphere

With sodium tetrahydroborate; Jones reagent; sodium azide; ozone; triethylamine; dicyclohexyl-carbodiimide; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1039/c1ob06632c

Reference yield:

: 1357622-43-5
(R)-2-((3-bromophenoxy)methyl)-3-formylamino-1-propanol

: 1357622-44-6
(S)-methyl 2-((3-bromophenoxy)methyl)-3-formylaminopropanoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: Jones reagent / acetone / 2 h / 0 °C / Inert atmosphere

1.2: pH 2 / Inert atmosphere

2.1: tetrahydrofuran / 0 °C / Inert atmosphere

With Jones reagent; In tetrahydrofuran; acetone;
DOI:10.1039/c1ob06632c