[Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)]

Base Information

• Chemical Name: [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)]
• CAS No.: 1353868-92-4
• Molecular Formula: C₃₃H₃₃FeN₂O₄PPdS
• Molecular Weight: 746.943
• Mol file: 1353868-92-4.mol

Synonyms:

Chemical Property of [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)]

There total 2 articles about [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

trans-{palladium((N,N-dimethylbenzylamine)-C2,N)(OAc)}2 + [triethylammonium][Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)] (1353868-75-3) → [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)] (1353868-92-4) + [triethylammonium][Pd(acetate)(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κP)]

Guidance literature:

In chloroform; byproducts: [CH3COO][HN(C2H5)3]; (Ar, dark); addn. of CHCl3 soln. of ferrocene deriv. to CHCl3 soln. of palladium compd., stirring for 24 h; concg., filtration through celite, layering with diethyl ether, keeping for several ds, filtration, washing with diethyl ether, drying in vac., elem. anal.;

DOI:10.1021/om2011529

Reference yield:

trans-{palladium((N,N-dimethylbenzylamine)-C2,N)(OAc)}2 + [triethylammonium][Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)] (1353868-75-3) → [Pd(2-[(dimethylamino-κN)methyl]phenyl-κC1)(Fe(C5H4P(C6H5)2)(C5H4CONHCH2SO3)-κ2P,O)] (1353868-92-4)

Guidance literature:

In d⁽⁴⁾-methanol; (Ar, dark); addn. of CD3OD soln. of ferrocene deriv. to palladium compd., stirring for 24 h;

DOI:10.1021/om2011529

upstream raw materials:

[triethylammonium][Fe(C₅H₄P(C₆H₅)2)(C₅H₄CONHCH₂SO₃)]