(2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe

Base Information

• Chemical Name: (2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe
• CAS No.: 219598-49-9
• Molecular Formula: C₂₅H₂₇F₃MoN₄
• Molecular Weight: 536.451
• Mol file: 219598-49-9.mol

Synonyms:

Chemical Property of (2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe

There total 1 articles about (2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

tetrachlorobis(tetrahydrofurano)molybdenum(IV) (16998-75-7) + 2,2',2''-tris(4-fluorophenylamino)triethylamine (219598-40-0) + methyllithium (917-54-4) → (2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe (219598-49-9)

Guidance literature:

In tetrahydrofuran; diethyl ether; byproducts: LiCl; under N2 atm. MoCl4(THF)2 was added to soln. amine in THF, stirred for 15 min., cooled to -40°C, MeLi in Et2O was added, react. mixt. wasallowed to warm to room temp. for 1 h; solvent was removed, residue was extd. with toluene, filtered, evapd., washed with Et2O and pentane, dried in vacuo, and crystd. from toluene; elem. anal.;

DOI:10.1021/ic001122v

Reference yield: 84.0%

(2,2',2''-tris(4-fluorophenylamino)triethylamine)MoMe (219598-49-9) + 2,6-lutidine hydrochloride (15439-85-7) → (2,2',2''-tris(4-fluorophenylphenylamino)triethylamine)MoCl (219598-53-5)

Guidance literature:

In tetrahydrofuran; under N2 atm. 2,6-lutidinium chloride was added to soln. complex in THF at -40°C, react. mixt. was allowed to warm to room temp. for 1 h; solvent was removed in vacuo, residue was washed with Et2O, toluene, andpentane;

DOI:10.1021/ic001122v

upstream raw materials:

tetrachlorobis(tetrahydrofurano)molybdenum(IV)

2,2',2''-tris(4-fluorophenylamino)triethylamine

methyllithium

Downstream raw materials:

(2,2',2''-tris(4-fluorophenylphenylamino)triethylamine)MoCl