4-BroMo-2,7-dihexylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Base Information

• Chemical Name: 4-BroMo-2,7-dihexylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone
• CAS No.: 1315605-26-5
• Molecular Formula: C₂₆H₂₉BrN₂O₄
• Molecular Weight: 513.431
• Mol file: 1315605-26-5.mol

Synonyms:

Chemical Property of 4-BroMo-2,7-dihexylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Chemical Property:

• Boiling Point: 645.7±50.0 °C(Predicted)
• PKA: -3.16±0.20(Predicted)
• Density: 1.375±0.06 g/cm3(Predicted)

Purity/Quality:

98.5% ^*data from raw suppliers

4-Bromo-2,7-dihexylbenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-BroMo-2,7-dihexylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

There total 4 articles about 4-BroMo-2,7-dihexylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

hexan-1-amine (111-26-2) + 2-bromo-1,4,5,8-naphthalenetetracarboxylic acid dianhydride (846-20-8) → N,N'-di(n-hexyl)-2-bromonaphthalene-1,4,5,8-bis(dicarboximide) (1315605-26-5)

Guidance literature:

With acetic acid; for 10.5h; Reflux;

Reference yield: 21.0%

hexan-1-amine (111-26-2) + 1,4,5,8-naphthalenetetracarboxylic dianhydride (81-30-1) → N,N'-di(n-hexyl)-2-bromonaphthalene-1,4,5,8-bis(dicarboximide) (1315605-26-5) + 4,9-dibromo-2,7-dihexylbenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (1239327-73-1)

Guidance literature:

1,4,5,8-naphthalenetetracarboxylic dianhydride; With sulfuric acid; at 85 ℃; for 0.5h;

With potassium 1,3-dibromoisocyanurate; at 85 ℃; for 20h;

hexan-1-amine; With acetic acid; for 0.333333h; Time; Concentration; Reflux;

Reference yield: 7.0%

hexan-1-amine (111-26-2) + naphthalene-1,4,5,8-tetracarboxydianhydride → N,N'-di(n-hexyl)-2-bromonaphthalene-1,4,5,8-bis(dicarboximide) (1315605-26-5)

Guidance literature:

naphthalene-1,4,5,8-tetracarboxydianhydride; With potassium 1,3-dibromoisocyanurate; sulfuric acid; at 85 ℃; for 20h;

hexan-1-amine; With acetic acid; for 0.333333h; Reflux;

DOI:10.1021/ol203432x

upstream raw materials:

hexan-1-amine

1,4,5,8-naphthalenetetracarboxylic dianhydride

2-bromo-1,4,5,8-naphthalenetetracarboxylic acid dianhydride