1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

Base Information

Chemical Name:1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate
CAS No.:1395311-87-1
Molecular Formula:CF₃O₃S*C₂₆H₃₂N₃O₂S
Molecular Weight:599.695
Hs Code.:

1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

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Chemical Property of 1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

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Technology Process of 1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

There total 8 articles about 1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 1395311-84-8
1-[4-(methoxycarbonyl)benzyl]-3,3,6,6-tetramethyl-4,5-didehydro-2,3,6,7-tetrahydrothiepinium trifluoromethanesulfonate

: 622-79-7
benzyl azide

: 1395311-87-1
1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

Guidance literature:: In acetonitrile; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1039/c2cc35034c

Reference yield:

: 2800-87-5
3,3,6,6-tetramethylthiepane-4,5-dione

: 1395311-87-1
1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1: hydrazine hydrochloride; hydrazine hydrate; ethylene glycol / ethanol

2: lead(IV) tetraacetate / dichloromethane

3: dichloromethane; water / 24 h / 20 °C / Inert atmosphere

4: acetonitrile / 2 h / 20 °C / Inert atmosphere

With hydrazine hydrochloride; lead(IV) tetraacetate; hydrazine hydrate; ethylene glycol; In ethanol; dichloromethane; water; acetonitrile;
DOI:10.1039/c2cc35034c

Reference yield:

: 55168-40-6,4485-40-9
5-hydroxy-3,3,6,6-tetramethylthiepan-4-one

: 1395311-87-1
1-benzyl-6-[4-(methoxycarbonyl)benzyl]-4,4,8,8-tetramethyl-4,5,7,8-tetrahydro-1H-thiepino[4,5-d][1,2,3]triazol-6-ium trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1: lead(IV) tetraacetate / pyridine

2: hydrazine hydrochloride; hydrazine hydrate; ethylene glycol / ethanol

3: lead(IV) tetraacetate / dichloromethane

4: dichloromethane; water / 24 h / 20 °C / Inert atmosphere

5: acetonitrile / 2 h / 20 °C / Inert atmosphere

With hydrazine hydrochloride; lead(IV) tetraacetate; hydrazine hydrate; ethylene glycol; In pyridine; ethanol; dichloromethane; water; acetonitrile;
DOI:10.1039/c2cc35034c