C₂₉H₃₄O₄Se

Base Information

• Chemical Name: C₂₉H₃₄O₄Se
• CAS No.: 1313396-42-7
• Molecular Formula: C₂₉H₃₄O₄Se
• Molecular Weight: 525.547
• Mol file: 1313396-42-7.mol

Synonyms:

Chemical Property of C₂₉H₃₄O₄Se

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₉H₃₄O₄Se

There total 12 articles about C₂₉H₃₄O₄Se which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(trichloromethyl) carbonate (32315-10-9) + C22H30O3 (1313396-41-6) + Benzeneselenol (645-96-5) → C29H34O4Se (1313396-42-7)

Guidance literature:

bis(trichloromethyl) carbonate; C₂₂H₃₀O₃; With pyridine; dmap; In tetrahydrofuran; benzene; at 30 ℃; for 3h; Inert atmosphere;

Benzeneselenol; In tetrahydrofuran; benzene; at 30 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c1cc11005e

Reference yield:

C20H36OSi (1313396-35-8) → C29H34O4Se (1313396-42-7)

Guidance literature:

Multi-step reaction with 7 steps

1.1: 3-chloro-benzenecarboperoxoic acid / ethyl acetate / 2 h / 0 °C / Inert atmosphere

2.1: 2,2,6,6-tetramethyl-piperidine; n-butyllithium; dimethylaluminum chloride / hexane; n-heptane; benzene / 2 h / 0 °C / Inert atmosphere

2.2: Inert atmosphere

3.1: sodium hydride / N,N-dimethyl-formamide / 0.83 h / 50 °C / Inert atmosphere

3.2: 5 h / 50 °C / Inert atmosphere

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 21 h / 40 °C / Inert atmosphere

5.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1.5 h / 25 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / hexane; dichloromethane / 2 h / -78 °C / Inert atmosphere

6.2: 0 °C / Inert atmosphere

7.1: pyridine; dmap / tetrahydrofuran; benzene / 3 h / 30 °C / Inert atmosphere

7.2: 16 h / 30 °C / Inert atmosphere

With pyridine; 2,2,6,6-tetramethyl-piperidine; dmap; n-butyllithium; tetrabutyl ammonium fluoride; dimethylaluminum chloride; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; n-heptane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; benzene;

DOI:10.1039/c1cc11005e

Reference yield:

C18H34OSi → C29H34O4Se (1313396-42-7)

Guidance literature:

Multi-step reaction with 9 steps

1.1: di(rhodium)tetracarbonyl dichloride / toluene / 50 h / 90 °C / 760.05 Torr

2.1: 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride / dichloromethane / 12 h / 25 °C / Inert atmosphere

2.2: -10 - 20 °C / Inert atmosphere

3.1: 3-chloro-benzenecarboperoxoic acid / ethyl acetate / 2 h / 0 °C / Inert atmosphere

4.1: 2,2,6,6-tetramethyl-piperidine; n-butyllithium; dimethylaluminum chloride / hexane; n-heptane; benzene / 2 h / 0 °C / Inert atmosphere

4.2: Inert atmosphere

5.1: sodium hydride / N,N-dimethyl-formamide / 0.83 h / 50 °C / Inert atmosphere

5.2: 5 h / 50 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 21 h / 40 °C / Inert atmosphere

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1.5 h / 25 °C / Inert atmosphere

8.1: diisobutylaluminium hydride / hexane; dichloromethane / 2 h / -78 °C / Inert atmosphere

8.2: 0 °C / Inert atmosphere

9.1: pyridine; dmap / tetrahydrofuran; benzene / 3 h / 30 °C / Inert atmosphere

9.2: 16 h / 30 °C / Inert atmosphere

With pyridine; 2,2,6,6-tetramethyl-piperidine; dmap; n-butyllithium; 2,6-di-tert-butyl-4-methylpyridine; di(rhodium)tetracarbonyl dichloride; trifluoromethylsulfonic anhydride; tetrabutyl ammonium fluoride; dimethylaluminum chloride; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; n-heptane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;

DOI:10.1039/c1cc11005e

upstream raw materials:

C₁₉H₃₄O₂Si

C₂₀H₃₆OSi

C₂₀H₃₆O₂Si

C₂₀H₃₆O₂Si

Downstream raw materials:

C₂₃H₃₀O₄

C₂₃H₃₂O₄

C₂₃H₃₀O₃