octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II)

Base Information

• Chemical Name: octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II)
• CAS No.: 111211-91-7
• Molecular Formula: C₁₅₈H₁₈₂Cu₂N₁₂
• Molecular Weight: 2376.36
• Mol file: 111211-91-7.mol

Synonyms:

Chemical Property of octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II)

There total 1 articles about octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin-2,3-dione + [(C6H3(C(CH3)3)2CC4H2N)3Cu(C6H3(C(CH3)3)2CC4O2N)] (214962-07-9) + 1,2,4,5-benzenetetraamine tetrahydrochloride (4506-66-5) → octakis(3',5'-di-tert-butylphenyl)bis-porphyrin copper(II) + octakis(3',5'-di-tert-butylphenyl)bis-porphyrin dicopper(II) (111211-91-7)

Guidance literature:

In pyridine; dichloromethane; porphyrin and tetraamine hyrdrochloride were refluxed for 0.5 h in dry pyridine under argon; copper porphyrin was added, refluxed under argon fro 16.5 h, CH2Cl2 added; organic soln. was washed, dried, solvent removed; chromd. (silica, CH2Cl2-petroleum);

DOI:10.1039/a907059a

upstream raw materials:

[(C₆H₃(C(CH₃)3)2CC₄H₂N)3Cu(C₆H₃(C(CH₃)3)2CC₄O₂N)]

1,2,4,5-benzenetetraamine tetrahydrochloride