Technology Process of <5,6-(13)C2>-4,7-Dihydro-2-phenyl-1,3-dioxepin
There total 1 articles about <5,6-(13)C2>-4,7-Dihydro-2-phenyl-1,3-dioxepin which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridinium p-toluenesulfonate;
In
benzene;
Yield given;
Heating;
DOI:10.1021/jo00126a052
- Guidance literature:
-
With
lithium aluminium tetrahydride; aluminium trichloride;
In
diethyl ether; dichloromethane;
Yield given;
1.) room temp., 1.25 h, 2.) reflux, 1.25 h;
DOI:10.1021/jo00126a052
- Guidance literature:
-
Multi-step reaction with 2 steps
1: LiAlH4, AlCl3 / CH2Cl2; diethyl ether / 1.) room temp., 1.25 h, 2.) reflux, 1.25 h
2: 4 Angstroem molecular sieves, titanium tetraisopropoxide, diisopropyl L-tartrate, tert-butyl hydroperoxide / CH2Cl2; decane / 1.) -23 deg C, 6 h, 2.) -20 to -15 deg C, 17 h
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; lithium aluminium tetrahydride; aluminium trichloride; L-(+)-diisopropyl tartrate; 4 A molecular sieve;
In
diethyl ether; decane; dichloromethane;
DOI:10.1021/jo00126a052
