2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate

Base Information

• Chemical Name: 2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate
• CAS No.: 1259929-94-6
• Molecular Formula: C₁₈H₂₄O₂
• Molecular Weight: 272.387
• Mol file: 1259929-94-6.mol

Synonyms:

Chemical Property of 2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate

There total 1 articles about 2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2.6-dimethylphenol (576-26-1,25134-01-4) + 3,7-dimethyloct-2,6-dienylacyl chloride (858251-08-8) → 2,6-dimethylphenyl (Z)-3,7-dimethyl-2,6-octadienoate + 2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate (1259929-94-6)

Guidance literature:

2.6-dimethylphenol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.25h; Inert atmosphere;

3,7-dimethyl-2,6-dioctenoyl chloride; In tetrahydrofuran; mineral oil; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol102674z

Reference yield:

2,6-dimethylphenyl (E)-3,7-dimethyl-2,6-octadienoate (1259929-94-6) + sodium tetraphenyl borate (143-66-8) → C24H30O2 (1259930-07-8) + C24H30O2 (1259930-08-9)

Guidance literature:

With methanol; C₄₂H₅₂Cl₂O₄Rh₂; In 1,4-dioxane; at 60 ℃; for 45h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ol102674z

upstream raw materials:

2.6-dimethylphenol

3,7-dimethyloct-2,6-dienylacyl chloride

Downstream raw materials:

C₂₄H₃₀O₂

C₂₄H₃₀O₂