[(Me₂C₆H₃)Xanthdim](Cu(MeCN))2

Base Information

• Chemical Name: [(Me₂C₆H₃)Xanthdim](Cu(MeCN))2
• CAS No.: 1269763-79-2
• Molecular Formula: C₆₅H₇₄Cu₂N₆O
• Molecular Weight: 1082.43
• Mol file: 1269763-79-2.mol

Synonyms:

Chemical Property of [(Me₂C₆H₃)Xanthdim](Cu(MeCN))2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(Me₂C₆H₃)Xanthdim](Cu(MeCN))2

There total 1 articles about [(Me₂C₆H₃)Xanthdim](Cu(MeCN))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene (896711-16-3) + copper (I) tert-butoxide (35342-67-7,35342-68-8) + acetonitrile (75-05-8,26809-02-9) → [(Me2C6H3)Xanthdim](Cu(MeCN))2 (1269763-79-2)

Guidance literature:

In acetonitrile; benzene; (under Ar, Schlenk); benzene suspn. of ligand and CuOC(CH3)3 added in MeCN, stirred for 18 h at room temp., treated with MeCN, stirred for 4 h at room temp.; filtered, dried under vac.; elem. anal.;

DOI:10.1021/ic101249k

Reference yield: 97.0%

carbon disulfide (75-15-0,12122-00-8) + [(Me2C6H3)Xanthdim](Cu(MeCN))2 (1269763-79-2) → (C(CH3)3)2C13H4O(CH3)2(C3H2N2(C6H3(CH3)2)2Cu)2CS2

Guidance literature:

In tetrahydrofuran; byproducts: CH3CN; 7.2 equiv. of CS2 added to soln. of Cu complex in THF, stirred for 5 minat room temp.; evapd., dried (vac.);

DOI:10.1039/c1cc11518a

Reference yield: 97.0%

[(Me2C6H3)Xanthdim](Cu(MeCN))2 (1269763-79-2) + [13C]carbon disulfide (30860-31-2) → (C(CH3)3)2C13H4O(CH3)2(C3H2N2(C6H3(CH3)2)2Cu)2(13)CS2

Guidance literature:

In tetrahydrofuran; byproducts: CH3CN; 7.2 equiv. of (13)CS2 added to soln. of Cu complex in THF, stirred for 5min at room temp.; evapd., dried (vac.);

DOI:10.1039/c1cc11518a

upstream raw materials:

2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-4,5-bis(1-(2,3-dimethylphenylamino)-3-(2,3-dimethylphenylimino)isopropenyl)xanthene

copper (I) tert-butoxide

acetonitrile