Technology Process of (+/-)-1-<(tert-Butyldiphenylsilyl)oxy>-6-iodo-3-methylhexane
There total 6 articles about (+/-)-1-<(tert-Butyldiphenylsilyl)oxy>-6-iodo-3-methylhexane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium iodide;
In
acetone;
for 8h;
Yield given;
Ambient temperature;
DOI:10.1021/jo00071a024
- Guidance literature:
-
Multi-step reaction with 5 steps
1: imidazole,, DMAP / CH2Cl2 / 5 h / Ambient temperature
2: 1.) O3, 2.) Me2S / 1.) CH2Cl2, MeOH, -78 deg C, 12 min, 2.) room temp., 8 h
3: LiAlH4 / diethyl ether / 8 h
4: Et3N / diethyl ether / 1 h / Ambient temperature
5: NaI / acetone / 8 h / Ambient temperature
With
1H-imidazole; dmap; lithium aluminium tetrahydride; dimethylsulfide; ozone; triethylamine; sodium iodide;
In
diethyl ether; dichloromethane; acetone;
DOI:10.1021/jo00071a024
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) O3, 2.) Me2S / 1.) CH2Cl2, MeOH, -78 deg C, 12 min, 2.) room temp., 8 h
2: LiAlH4 / diethyl ether / 8 h
3: Et3N / diethyl ether / 1 h / Ambient temperature
4: NaI / acetone / 8 h / Ambient temperature
With
lithium aluminium tetrahydride; dimethylsulfide; ozone; triethylamine; sodium iodide;
In
diethyl ether; acetone;
DOI:10.1021/jo00071a024
