CH₃(C₆H₅)GeHCH₂Cl

Base Information

• Chemical Name: CH₃(C₆H₅)GeHCH₂Cl
• CAS No.: 74858-01-8
• Molecular Formula: C₈H₁₁ClGe
• Molecular Weight: 215.218
• Mol file: 74858-01-8.mol

Synonyms:

Chemical Property of CH₃(C₆H₅)GeHCH₂Cl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CH₃(C₆H₅)GeHCH₂Cl

There total 2 articles about CH₃(C₆H₅)GeHCH₂Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

CH3(C6H5)GeHCHCl2 + tri-n-butyl-tin hydride (688-73-3) → CH3(C6H5)GeHCH2Cl (74858-01-8)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); Bu3SnH was added to Ge compd. and react. initiated by UV irradn. (248-436 nm); mixt. was sepd. by distn.;

DOI:10.1016/S0022-328X(00)83698-0

Reference yield: 42.0%

methylphenylchlorogermane (58276-72-5) + (dichloromethyl)lithium (2146-67-0) → CH3(C6H5)GeHCH2Cl (74858-01-8)

Guidance literature:

In diethyl ether; soln. of Ge compd. was dropped to LiCHCl2 at -90°C, mixt. was stirred for 2 h at the same temp. and then warmed up to room temp.; hydrolysis, extn. with pentane, drying over Na2SO4 and distn.;

DOI:10.1016/S0022-328X(00)83698-0

upstream raw materials:

methylphenylchlorogermane

(dichloromethyl)lithium

tri-n-butyl-tin hydride